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Merck
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문서

92361

Sigma-Aldrich

Chlorotrimethylsilane

≥98.0% (GC)

동의어(들):

TMCS, Trimethylchlorosilane, Trimethylsilyl chloride

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About This Item

Linear Formula:
(CH3)3SiCl
CAS Number:
75-77-4
Molecular Weight:
108.64
Beilstein:
1209232
EC Number:
200-900-5
MDL number:
MFCD00000502
UNSPSC 코드:
12352302
PubChem Substance ID:
57653472
NACRES:
NA.22

vapor density

3.7 (vs air)

vapor pressure

100 mmHg ( 25 °C)

분석

≥98.0% (GC)

형태

liquid

autoignition temp.

752 °F

expl. lim.

6.4 %

refractive index

n20/D 1.387 (lit.)

bp

57 °C (lit.)

mp

−40 °C (lit.)

density

0.856 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(C)Cl

InChI

1S/C3H9ClSi/c1-5(2,3)4/h1-3H3

InChI key

IJOOHPMOJXWVHK-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

일반 설명

Chlorotrimethylsilane is a chloro-organosilane compound mainly used for silylation reactions.

애플리케이션

Chlorotrimethylsilane has been used to silanize glass surface to make them more hydrophobic. It can be used in combination with hexamethyldisilazane for the protection of alcohols by forming trimethylsilyl ethers via silylation reaction. Also used in Fisher Glycosylation

픽토그램

FlameSkull and crossbonesCorrosion
GHS02,GHS06,GHS05

신호어

Danger

유해 및 위험 성명서

H225,H301 + H331,H312,H314

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A

보충제 위험성

EUH014

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point (°F)

-18.4 °F - closed cup

Flash Point (°C)

-28 °C - closed cup

개인 보호 장비

Faceshields, Gloves, Goggles

시험 성적서(COA)

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문서 라이브러리 방문

Science of Synthesis: Houben-Weyl Methods of Molecular Transformations, 4, 261-261 (2014)
Thermal analysis of disulfonated poly (arylene ether sulfone) plasticized with poly (ethylene glycol) for membrane formation.
Oh HJ, et al.
Polymer, 55(1), 235-247 (2014)
Yongju Kwon et al.
Nature communications, 11(1), 3127-3127 (2020-06-21)
Magic-sized clusters (MSCs) can be isolated as intermediates in quantum dot (QD) synthesis, and they provide pivotal clues in understanding QD growth mechanisms. We report syntheses for two families of heterogeneous-atom-incorporated InP MSCs that have chlorine or zinc atoms. All
Yuma Komata et al.
Chemistry, an Asian journal, 11(22), 3225-3233 (2016-10-21)
Alkoxychlorosilanes are scientifically and industrially important toward preparing silicone and silica as well as preparation of siloxane-based nanomaterials by stepwise reactions of Si-OR (R=alkyl) and Si-Cl groups. Intermolecular exchange of alkoxy and chloro groups between alkoxysilanes and chlorosilanes (functional group
Use of organosilicon reagents as protective groups in organic synthesis.
Lalonde M & Chan TH.
Synthesis, 1985(09), 817-845 (1985)
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