8.22256

Aniline

for synthesis

• 동의어(들): Aniline, Aminobenzene, Phenylamine, Benzenamine
• 실험식(Hill 표기법): C₆H₇N
• CAS Number: 62-53-3
• Molecular Weight: 93.13
• MDL number: MFCD00007629
• UNSPSC 코드: 12352116
• EC 인덱스 번호: 200-539-3
• NACRES: NA.22

속성

• vapor pressure: 0.5 hPa ( 20 °C)
• Quality Level: 200
• 분석: ≥99.0% (GC)
• 형태: liquid
• autoignition temp.: 540 °C
• 효능: 840 mg/kg LD₅₀, skin (Rabbit)
• expl. lim.: 1.2-11 % (v/v)
• pH: 8.8 (20 °C, 36 g/L in H₂O)
• bp: 184 °C/1013 hPa
• mp: -6.2 °C
• 전이 온도: flash point 76 °C
• solubility: 36 g/L
• density: 1.02 g/cm³ at 20 °C
• 저장 온도: 2-30°C
• InChI: 1S/C6H7N/c7-6-4-2-1-3-5-6/h1-5H,7H2
• InChI key: PAYRUJLWNCNPSJ-UHFFFAOYSA-N

설명

애플리케이션

• One pot conversion of phenols and anilines to aldehydes and ketones: Exploiting α gem boryl carbanions, this study offers a method compatible with a diverse range of phenols and anilines, facilitating simpler synthetic pathways in organic chemistry (Das et al., 2024).
• In-silico-assisted derivatization of triarylboranes: This research discusses a catalytic method for the reductive alkylation of aniline-derived amino acids, improving functional-group compatibility in peptide modification (Hisata et al., 2024).
• C–heteroatom coupling with electron-rich aryls: Utilizing nickel catalysis and light, this method enhances the synthesis of anilines and aryl ethers, contributing to more efficient organic synthesis processes (Cornella et al., 2024).

분석 메모

Assay (GC, area%): ≥ 99.0 % (a/a)
Density (d 20 °C/ 4 °C): 1.020 - 1.022
Identity (IR): passes test

안전성 정보

• 픽토그램: GHS06,GHS08,GHS05,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H301 + H311 + H331,H317,H318,H341,H351,H372,H410
• 예방조치 성명서: P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Muta. 2 - Skin Sens. 1 - STOT RE 1
• 표적 기관: Blood
• Storage Class Code: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flash Point (°F): 158.0 °F - closed cup
• Flash Point (°C): 70 °C - closed cup