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Merck
모든 사진(4)

문서

237973

Sigma-Aldrich

Aluminum nitrate nonahydrate

ACS reagent, ≥98%

동의어(들):

Aluminium nitrate

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About This Item

Linear Formula:
Al(NO3)3 · 9H2O
CAS Number:
Molecular Weight:
375.13
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NB.24

Grade

ACS reagent

Quality Level

분석

≥98%
98.0-102.0% (ACS specification)

형태

crystals

반응 적합성

reagent type: catalyst
core: aluminum

불순물

≤0.005% insolubles

pH

2.5-3.5 (25 °C, 50 g/L)

mp

73 °C (lit.)

음이온 미량물

chloride (Cl-): ≤0.001%
sulfate (SO42-): ≤0.005%

양이온 미량물

Ca: 0.005%
Fe: ≤0.002%
K: 0.002%
Mg: 0.001%
Na: 0.005%
heavy metals: ≤0.001% (by ICP-OES)

SMILES string

O.O.O.O.O.O.O.O.O.[Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Al.3NO3.9H2O/c;3*2-1(3)4;;;;;;;;;/h;;;;9*1H2/q+3;3*-1;;;;;;;;;

InChI key

SWCIQHXIXUMHKA-UHFFFAOYSA-N

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일반 설명

Aluminum nitrate nonahydrate is an aluminum salt that can be prepared by dissolving aluminum or aluminum hydroxide in dilute nitric acid. It is used in the preparation of insulating papers, transformer core laminates, and cathode-ray tube heating elements.

애플리케이션

Aluminum nitrate nonahydrate can be used as a catalyst to synthesize:
  • β-Amino carbonyl compounds via one-pot Mannich reaction.
  • Bis(indolyl)methanes via electrophilic substitution reaction of indoles with aromatic aldehydes.
  • 3,4-Dihydropyrimidinones via solvent-free Biginelli reaction.

특징 및 장점

  • Easily recoverable through simple phase separation
  • Reusable without a distinct loss of catalytic activity

픽토그램

Corrosion

신호어

Danger

유해 및 위험 성명서

예방조치 성명서

Hazard Classifications

Eye Dam. 1

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point (°F)

does not flash

Flash Point (°C)

does not flash


시험 성적서(COA)

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문서 라이브러리 방문

Mechanism of thermal decomposition and ?-pyrolysis of aluminum nitrate nonahydrate [Al (NO3)3? 9H2O].
El-Shereafy E, et al.
J. Radioanal. Nucl. Chem., 237(1-2), 183-186 (1998)
Okada et al.
Journal of colloid and interface science, 219(1), 195-200 (1999-10-21)
Amorphous aluminosilicate xerogels with various chemical compositions were prepared by coprecipitation, and their surface acidity and hydrophilicity were investigated by NH(3) gas temperature programed desorption (TPD), water vapor adsorption-desorption isotherms, and (27)Al magic angle spinning nuclear magnetic resonance (MAS NMR).
Macro-micro relationship in nanostructured functional
Composites
Zanotto A, et al.
Express Polymer Letters, 6(5), 410-416 (2012)
Preparation of mullite fibers from aluminum isopropoxide-aluminum nitrate-tetraethylorthosilicate solutions by sol-gel method.
Song KC.
Materials Letters, 35(5), 290-296 (1998)
Effect of preparation conditions on the porous properties of coprecipitated Al2O3-SiO2 xerogels synthesized from aluminium nitrate nonahydrate and tetraethylorthosilicate.
Okada K, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 37(3), 355-364 (2000)

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