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230022

Sigma-Aldrich

Zinc bromide

99.999% trace metals basis

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Synonym(s):
Zinc dibromide
Linear Formula:
ZnBr2
CAS Number:
Molecular Weight:
225.20
EC Number:
MDL number:
eCl@ss:
38150410
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

99.999% trace metals basis

form

powder and chunks

reaction suitability

reagent type: catalyst
core: zinc

impurities

≤15.0 ppm Trace Metal Analysis

bp

~670 °C/1 atm (lit.)

mp

394 °C (lit.)

solubility

diethyl ether: slightly soluble(lit.)
ethanol: very soluble(lit.)

SMILES string

Br[Zn]Br

InChI

1S/2BrH.Zn/h2*1H;/q;;+2/p-2

InChI key

VNDYJBBGRKZCSX-UHFFFAOYSA-L

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Application

Zinc bromide supported on silica or montmorillonite can be used as a selective catalyst for the bromination of aromatic substrates.

It can be used as starting material to prepare poly(ethylene oxide)/ zinc salt systems, which can be used as polymer electrolytes.

Itcan also be used to prepare ZnO nanoparticles.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

Storage Class

8A - Combustible, corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Franz, A.K. Woerpel, K.A.
Journal of the American Chemical Society, 121, 949-949 (1999)
Frederic G Buono et al.
Organic letters, 10(23), 5325-5328 (2008-11-05)
Kinetic studies using reaction calorimetry were conducted under synthetically relevant conditions to study the effect of additives in the cyanation of bromobenzene catalyzed by palladium complexes. This work demonstrates that the addition of a catalytic amount of ZnBr(2) facilitates the
Toshiaki Sasada et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(34), 9385-9394 (2011-07-23)
The [5+1] annulation of enamidines, which were prepared from functionalized silanes, organolithium compounds and two nitriles, with N,N-dimethylformamide dialkyl acetals as the C1 unit is described, leading to the synthesis of tri- and tetrasubstituted pyrimidine derivatives under catalyst- and solvent-free
Direct synthesis of alkynylstannanes: ZnBr2 catalyst for the reaction of tributyltin methoxide and terminal alkynes.
Kensuke Kiyokawa et al.
Angewandte Chemie (International ed. in English), 50(44), 10393-10396 (2011-09-15)
Isabelle Aillaud et al.
Molecules (Basel, Switzerland), 15(11), 8144-8155 (2010-11-13)
A methodological study devoted to the Mannich-like multicomponent synthesis of the antiplatelet agent (±)‑clopidogrel (7) and the ethyl ester analogue 6 is described. The process involves the formation of 2-chlorophenyl zinc bromide (2) and its subsequent reaction with an alkyl

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