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262064

Sigma-Aldrich

mono-Bromoborane methyl sulfide complex solution

1.0 M in methylene chloride

Synonym(s):

Bromo(dimethyl sulfide)borane, Bromo(dimethyl sulfide)dihydroboron

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About This Item

Linear Formula:
(CH3)2S·BH2Br
CAS Number:
Molecular Weight:
154.86
MDL number:
UNSPSC Code:
12352112
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

reaction suitability

reagent type: reductant

concentration

1.0 M in methylene chloride

density

1.347 g/mL at 25 °C

SMILES string

BBr.CSC

InChI

1S/C2H6S.BBrH2/c1-3-2;1-2/h1-2H3;1H2

InChI key

AQRNIOMHNXJPFD-UHFFFAOYSA-N

Application

Reactant for:
  • Substitution reactions for synthesis of N-heterocyclic carbene boranes with boron-heteroatom bonds
  • Hydroboration reactions
  • Regio- and chemoselective brominative cleavage of terminal epoxides

signalword

Danger

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

target_organs

Central nervous system

supp_hazards

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 3

flash_point_f

50.0 °F

flash_point_c

10 °C


Certificates of Analysis (COA)

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Boryl halide, carboxylate and sulfonate complexes of 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (dipp-Imd-BH(2)X, X = halide or sulfonate) have been prepared from the parent borane dipp-Imd-BH(3) by (1) substitution reactions with R-X (X = halide or sulfonate), (2) reactions with electrophiles (like I(2) or
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