339830

2-[(Acetoxymethyl)allyl]trimethylsilane

99%

• Synonym(s): 2-(Trimethylsilylmethyl)-2-propen-1-yl acetate, 2-(Trimethylsilylmethyl)allyl acetate, 2-Acetoxymethyl-3-(trimethylsilyl)propene
• Linear Formula: CH₃CO₂CH₂C(=CH₂)CH₂Si(CH₃)₃
• CAS Number: 72047-94-0
• Molecular Weight: 186.32
• Beilstein/REAXYS Number: 1933657
• MDL number: MFCD00075170
• UNSPSC Code: 12352100
• PubChem Substance ID: 24860688
• NACRES: NA.22

Properties

• assay: 99%
• form: liquid
• refractive index: n20/D 1.440 (lit.)
• bp: 95 °C/7 mmHg (lit.)
• density: 0.877 g/mL at 25 °C (lit.)
• functional group: ester
• SMILES string: CC(=O)OCC(=C)C[Si](C)(C)C
• InChI: 1S/C9H18O2Si/c1-8(6-11-9(2)10)7-12(3,4)5/h1,6-7H2,2-5H3
• InChI key: IKQWABMHZKGCLX-UHFFFAOYSA-N

Description

Application

2-[(Acetoxymethyl)allyl]trimethylsilane was used in the cyclopentane synthesis via Pd(0)-catalyzed reactions with 2π acceptors.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: 159.8 °F - closed cup
• flash_point_c: 71 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter