341568
Benzeneruthenium(II) chloride dimer
Synonym(s):
(Benzene)dichlororuthenium dimer, Benzeneruthenium dichloride dimer, Bis(benzene)tetrachlorodiruthenium, Bis[(benzene)dichlororuthenium], Dibenzenetetrachlorodiruthenium
About This Item
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reaction suitability
core: ruthenium
reagent type: catalyst
SMILES string
Cl[Ru]Cl.Cl[Ru]Cl.c1ccccc1.c2ccccc2
InChI
1S/2C6H6.4ClH.2Ru/c2*1-2-4-6-5-3-1;;;;;;/h2*1-6H;4*1H;;/q;;;;;;2*+2/p-4
InChI key
YGXMUPKIEHNBNQ-UHFFFAOYSA-J
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Application
- Catalyst for SNAr reactions of fluoroarenes and cyclic amines (eq. 1)
- Precatalyst for the hydrogenation of β-keto esters (eq. 2)
- Precursor for the preparation of other ruthenium catalysts (eq. 3)
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Articles
Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.
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