733210
Tetrakis(dimethylsulfoxide)dichlororuthenium(II)
96%
Synonym(s):
Dichlorotetrakis(dimethyl sulfoxide)ruthenium
Sign Into View Organizational & Contract Pricing
All Photos(1)
About This Item
Recommended Products
Quality Level
assay
96%
form
solid
reaction suitability
core: ruthenium
reagent type: catalyst
mp
192-198 °C
SMILES string
O=S(C)C.O=S(C)C.Cl[Ru](Cl)O=S(C)C.O=S(C)C
InChI
1S/4C2H6OS.2ClH.Ru/c4*1-4(2)3;;;/h4*1-2H3;2*1H;/q;;;;;;+2/p-2
InChI key
UMJDEUKQHKMAOI-UHFFFAOYSA-L
General description
Tetrakis(dimethylsulfoxide)dichlororuthenium(II), [RuCl2(dmso)4] is an organoruthenium compound. It is used as a homogeneous catalyst in organic synthesis.
Tetrakis(dimethylsulfoxide)dichlororuthenium(II) (Ru(DMSO)4Cl2) is a coordination complex generally used as a catalyst in various reactions. In addition, it is also used as a precursor in the synthesis of other ruthenium complexes.
Tetrakis(dimethylsulfoxide)dichlororuthenium(II) (Ru(DMSO)4Cl2) is a coordination complex generally used as a catalyst in various reactions. In addition, it is also used as a precursor in the synthesis of other ruthenium complexes.
Application
RuCl2(dmso)4 can be used as a catalyst for:
Tetrakis(dimethylsulfoxide)dichlororuthenium(II) can be used as a precursor in the synthesis of Ru(II)-MEPE (metallo-supramolecular polyelectrolytes) complex, which is used to prepare electrochromic organic-metallic hybrid polymers.
- The β-alkylation of secondary alcohols via hydrogen auto-transfer process.
- The oxidation of thioethers (S) to sulfoxides by N-methylmorpholine N-oxide (NMO).
Tetrakis(dimethylsulfoxide)dichlororuthenium(II) can be used as a precursor in the synthesis of Ru(II)-MEPE (metallo-supramolecular polyelectrolytes) complex, which is used to prepare electrochromic organic-metallic hybrid polymers.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Customers Also Viewed
Evolution of physical and photocatalytic properties of new Zn (II) and Ru (II) complexes
Polyhedron, 170, 412-423 (2019)
Highly enantioselective and cis-diastereoselective cyclopropanation of olefins catalyzed by ruthenium complexes of (iminophosphoranyl) ferrocenes
Tetrahedron Letters, 48(45), 8014-8017 (2007)
Electrochromic solid-state devices using organic-metallic hybrid polymers
Journal of Inorganic and Organometallic Polymers and Materials, 19, 74-78 (2009)
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service