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733202

Sigma-Aldrich

cis-Dichlorobis(2,2′-bipyridine)ruthenium(II)

97%

Synonym(s):

cis-Bis(2,2′-bipyridine)dichlororuthenium(II) hydrate, cis-Ru(bpy)2Cl2.xH2O

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About This Item

Empirical Formula (Hill Notation):
C20H16Cl2N4Ru · xH2O
CAS Number:
Molecular Weight:
484.34 (anhydrous basis)
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

97%

form

powder

reaction suitability

core: ruthenium
reagent type: catalyst

mp

475.2-493.3

SMILES string

[H]O[H].Cl[Ru]Cl.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4

InChI

1S/2C10H8N2.2ClH.H2O.Ru/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;;/h2*1-8H;2*1H;1H2;/q;;;;;+2/p-2

InChI key

XBOQABVNRXVAKI-UHFFFAOYSA-L

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Application

cis-Dichlorobis(2,2′-bipyridine)ruthenium(II) can be used in synthesizing a variety of ruthenium complexes such as ruthenium(II) complex that can modify the surface of gold nanoparticles for the cysteine detection by selective luminescence. It can also be used in the preparation of ruthenium complexes to design photochromic molecular switches and self-assembling supramolecular systems.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Photoinduced electron transfer in a triad that can be assembled/disassembled by two different external inputs. Toward molecular-level electrical extension cables.
Ballardini R, et al.
Journal of the American Chemical Society, 124(43), 12786-12795 (2002)
Simple and selective sensing of cysteine using gold nanoparticles modified by Ruthenium (II) complexes.
Li M J, et al.
Journal of Nanoscience and Nanotechnology, 11(4), 3578-3585 (2011)
Femtosecond isomerization in a photochromic molecular switch.
Mockus N V, et al.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 120(8), 1480-1483 (2008)

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