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Pentamethylcyclopentadienyliridium(III) chloride,dimer

greener alternative

96%

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Synonym(s):
di-μ-chlorodichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-iridium
Empirical Formula (Hill Notation):
C20H30Cl4Ir2
CAS Number:
Molecular Weight:
796.70
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

96%

form

solid

reaction suitability

core: iridium
reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

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SMILES string

Cl[Ir]Cl.Cl[Ir]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C

InChI

1S/2C10H15.4ClH.2Ir/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4

InChI key

JDOHSXHCQARCAW-UHFFFAOYSA-J

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This Item
656577225487767727
form

solid

form

solid

form

solid

form

solid

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

100

assay

96%

assay

97%

assay

99%

assay

97%

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative category

Aligned,

greener alternative category

Aligned,

greener alternative category

, Aligned

greener alternative category

, Aligned

General description

Pentamethylcyclopentadienyliridium(III) chloride, dimer is utilized as a catalyst in cross-coupling and dimerization reactions.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Catalyst for greener amine synthesis from amines and alcohols by hydrogen-borrowing. Precursor to cooperative metal-Bronsted acid catalyst for greener reductive amination using hydrogen gas.

Metal-Brønsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

Development of GSK's reagent guides – embedding sustainability into reagent selection

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Total Synthesis of Calothrixins A and B by Palladium-Catalyzed Tandem Cyclization/Cross-Coupling Reaction of Indolylborate
T Abe, et al.
European Journal of Organic Chemistry, 2012, 5018-5027 (2012)

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