Potassium diphenylphosphide solution

Name: Potassium diphenylphosphide solution
Brand: ALDRICH

0.5 M in THF, liquid

Synonym(s):

Potassium diphenylphosphine, Diphenylphosphine potassium salt, KPPh₂

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About This Item

Linear Formula:

(C₆H₅)₂PK

CAS Number:

15475-27-1

Molecular Weight:

224.28

UNSPSC Code:

12352002

NACRES:

NA.22

PubChem Substance ID:

24863767

MDL number:

MFCD00134530

Beilstein/REAXYS Number:

4164304

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Properties

Product Name

Potassium diphenylphosphide solution, 0.5 M in THF

form

liquid

Quality Level

100

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

concentration

0.5 M in THF

density

0.929 g/mL at 25 °C

functional group

phosphine

SMILES string

[K]P(c1ccccc1)c2ccccc2

InChI

1S/C12H10P.K/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1

InChI key

FCLYZQXPJKJTDR-UHFFFAOYSA-N

Description

Application

Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta5: eta1-C5Me4CH2PPh2)Re(CO)2.: This study explores the synthesis and reactivity of a novel phosphino complex, utilizing Potassium diphenylphosphide as a key reagent. The research highlights the molecular structure and potential applications in organometallic chemistry (Godoy et al., 2009).

Improved and efficient synthesis of chiral N,P-ligands via cyclic sulfamidates for asymmetric addition of butyllithium to benzaldehyde.: This paper details an improved synthesis method for chiral N,P-ligands using Potassium diphenylphosphide. The research demonstrates the compound′s efficacy in asymmetric synthesis, offering potential advancements in drug discovery and development (Rönnholm et al., 2007).

Coordination chemistry of diselenophosphinate complexes: the X-ray single-crystal structures of [K(Se2PPh2)(THF)2]2 and [In(Se2PPh2)3].L (L = THF, PhMe).: This article investigates the coordination chemistry involving diselenophosphinate complexes, with Potassium diphenylphosphide playing a crucial role. The study provides detailed X-ray crystallographic data, offering insights for future research in chemical synthesis and materials science (Davies et al., 2004).