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Alane N,N-dimethylethylamine complex solution

0.5 M in toluene

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Synonym(s):
(Ethyldimethylamine)trihydroaluminum, Dimethylethylamine alane
Linear Formula:
C2H5N(CH3)2 · AlH3
CAS Number:
Molecular Weight:
103.14
MDL number:
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

reaction suitability

reagent type: reductant

concentration

0.5 M in toluene

density

0.837 g/mL at 25 °C

SMILES string

[AlH3].CCN(C)C

InChI

1S/C4H11N.Al.3H/c1-4-5(2)3;;;;/h4H2,1-3H3;;;;

InChI key

CXNFERZVFRNSPE-UHFFFAOYSA-N

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140732D98203386391
vibrant-m

D98203

N,N-Diethylmethylamine

vibrant-m

386391

N-Ethylisopropylamine

reaction suitability

reagent type: reductant

reaction suitability

-

reaction suitability

-

reaction suitability

-

density

0.837 g/mL at 25 °C

density

0.897 g/mL at 25 °C (lit.)

density

0.72 g/mL at 25 °C (lit.)

density

0.72 g/mL at 25 °C (lit.)

form

liquid

form

liquid

form

liquid

form

liquid

concentration

0.5 M in toluene

concentration

-

concentration

-

concentration

-

Application

Alane N,N-dimethylethylamine complex solution can be used as a selective reducing agent for the reduction of brominated γ-lactams to synthesize dihydroflustramine C and flustramine E alkaloids.
Reactant for:
  • Preparation of aluminum nanoparticles
  • Fluorination reactions
  • Aluminum metal-organic chemical vapor deposition for the growth of aluminum films
  • Ligand-exchange reactions
  • Hydroalumination of nitriles and isonitriles

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 2

target_organs

Central nervous system

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk_germany

WGK 3

flash_point_f

-4.0 °F

flash_point_c

-20 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Customers Also Viewed

Hossein Robatjazi et al.
Science advances, 5(2), eaav5340-eaav5340 (2019-02-21)
Metal-organic frameworks (MOFs) and metal nanoparticles are two classes of materials that have received considerable recent attention, each for controlling chemical reactivities, albeit in very different ways. Here, we report the growth of MOF shell layers surrounding aluminum nanocrystals (Al
First total syntheses of dihydroflustramine C and flustramine E, alkaloids from the marine bryozoan Flustra foliacea.
Morales-Rios MS, et al.
Tetrahedron, 58(8), 1479-1484 (2002)

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