400386
Alane N,N-dimethylethylamine complex solution
0.5 M in toluene
Synonym(s):
(Ethyldimethylamine)trihydroaluminum, Dimethylethylamine alane
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About This Item
Linear Formula:
C2H5N(CH3)2 · AlH3
CAS Number:
Molecular Weight:
103.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
Form:
liquid
form
liquid
Quality Level
reaction suitability
reagent type: reductant
concentration
0.5 M in toluene
density
0.837 g/mL at 25 °C
functional group
amine
SMILES string
[AlH3].CCN(C)C
InChI
1S/C4H11N.Al.3H/c1-4-5(2)3;;;;/h4H2,1-3H3;;;;
InChI key
CXNFERZVFRNSPE-UHFFFAOYSA-N
Application
Reactant for:
- Preparation of aluminum nanoparticles
- Fluorination reactions
- Aluminum metal-organic chemical vapor deposition for the growth of aluminum films
- Ligand-exchange reactions
- Hydroalumination of nitriles and isonitriles
Alane N,N-dimethylethylamine complex solution can be used as a selective reducing agent for the reduction of brominated γ-lactams to synthesize dihydroflustramine C and flustramine E alkaloids.
signalword
Danger
target_organs
Central nervous system
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
-4.0 °F
flash_point_c
-20 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 2 Inhalation - STOT SE 3 - Water-react. 2
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First total syntheses of dihydroflustramine C and flustramine E, alkaloids from the marine bryozoan Flustra foliacea.
Morales-Rios MS, et al.
Tetrahedron, 58(8), 1479-1484 (2002)
Hossein Robatjazi et al.
Science advances, 5(2), eaav5340-eaav5340 (2019-02-21)
Metal-organic frameworks (MOFs) and metal nanoparticles are two classes of materials that have received considerable recent attention, each for controlling chemical reactivities, albeit in very different ways. Here, we report the growth of MOF shell layers surrounding aluminum nanocrystals (Al
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 400386-100ML | 04061838127136 |
| 400386-50ML | 04061831984927 |