514330
Methyllithium solution
3.1 M in diethoxymethane
Synonym(s):
Lithium methanide, MeLi
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About This Item
Empirical Formula (Hill Notation):
CH3Li
CAS Number:
Molecular Weight:
21.98
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587162
Concentration:
3.1 M in diethoxymethane
Form:
liquid
form
liquid
Quality Level
concentration
3.1 M in diethoxymethane
density
0.846 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
[Li]C
InChI
1S/CH3.Li/h1H3;
InChI key
DVSDBMFJEQPWNO-UHFFFAOYSA-N
Application
Methyllithium solution ( 3.1 M in diethoxymethane) can undergo 1,2-addition to benzaldehyde catalyzed by a 2-(2-hydroxyaryl)alcohol (HAROL) ligand in the presence of titanium isopropoxide to form (S)-1-phenylethan-1-ol.
Packaging
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Disclaimer
Product might have solid or sediment in the bottom of the bottle.
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signalword
Danger
hcodes
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 1
flash_point_f
5.0 °F - closed cup
flash_point_c
-15 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react. 1
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Chiral 2-(2-hydroxyaryl) alcohols (HAROLs) with a 1, 4-diol scaffold as a new family of ligands and organocatalysts.
Dilek O, et al.
Tetrahedron, 74(2), 268-286 (2018)
Erik Selander et al.
Proceedings of the National Academy of Sciences of the United States of America, 112(20), 6395-6400 (2015-04-29)
Interactions among microscopic planktonic organisms underpin the functioning of open ocean ecosystems. With few exceptions, these organisms lack advanced eyes and thus rely largely on chemical sensing to perceive their surroundings. However, few of the signaling molecules involved in interactions
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 514330-100ML | 04061832492872 |
| 514330-1L | 04061837882203 |
| 514330-4X25ML | 04061837882210 |