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Sigma-Aldrich

Ytterbium(III) trifluoromethanesulfonate

99.99%

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Synonym(s):
Yb(OTf)3, Trifluoromethanesulfonic acid ytterbium(III) salt, Yb(TFA)3, Ytterbium(III) triflate
Linear Formula:
(CF3SO3)3Yb
CAS Number:
Molecular Weight:
620.25
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

99.99%

reaction suitability

core: ytterbium
reagent type: catalyst

SMILES string

FC(F)(F)S(=O)(=O)O[Yb](OS(=O)(=O)C(F)(F)F)OS(=O)(=O)C(F)(F)F

InChI

1S/3CHF3O3S.Yb/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3

InChI key

AHZJKOKFZJYCLG-UHFFFAOYSA-K

Related Categories

Application

A water-tolerant Lewis acid catalyst recently used in one-pot syntheses of β-lactams, and in stereocontrolled radical and nucleophilic addition reactions. Catalyzes the synthesis of deoxypenostatin A in a novel, stereoselective, intramolecular Diels-Alder reaction.
Lewis acid catalyst used with a silylated chinchona alkaloid in an asymmetric synthesis of substituted β-lactams from an acid chloride and aryl imine. Also used to catalyze an aldehyde-ene reaction in a synthesis of the guaiane skeleton.
An important Lewis acid catalyst for a variety of synthetic reactions, including allylborations.

wgk_germany

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves


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