442151
Indium(III) trifluoromethanesulfonate
solid
Synonym(s):
In(OTf)3, In(TFA)3, Indium(III) triflate, Trifluoromethanesulfonic acid indium(III) salt, Tris(trifluoromethanesulfonato)indium
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About This Item
Linear Formula:
(CF3SO3)3In
CAS Number:
Molecular Weight:
562.03
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Product Name
Indium(III) trifluoromethanesulfonate,
form
solid
Quality Level
reaction suitability
core: indium, reagent type: catalyst
SMILES string
[In+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
InChI
1S/3CHF3O3S.In/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3
InChI key
UCYRAEIHXSVXPV-UHFFFAOYSA-K
Application
Reactant or reagent involved in:
Catalyst for synthesis of benzoxazoles via cyclocondensations
- Synthesis of stable indium bacteriochlorins
- Studying basicities of phosphoryl compounds toward triflates Lewis acids
- Preparation of decahydroquinoline-type toxins via intramolecular hetero Diels-Alder reactions
Catalyst for synthesis of benzoxazoles via cyclocondensations
Reagent used a Lewis acid catalyst in organic synthesis and as a co-catalyst in catalysis.
Storage Class
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Trost, B. M.; Portnoy, M.; Kurihara, H.
Journal of the American Chemical Society, 118, 836-836 (1997)
Yadav, J. S.; Reddy, B. V. S. et al.
Tetrahedron Letters, 43, 1565-1565 (2002)
Guillaume Compain et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 18(6), 683-691 (2017-01-18)
Metal triflates, often called Lewis superacids, are potent catalysts for organic synthesis. However, the reactivity of a given Lewis superacid toward a given base is difficult to anticipate. A systematic screening of catalysts is often necessary when developing synthetic methodologies.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 442151-5G | 04061832282435 |
| 442151-25G | 04061833509777 |