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Copper(II) trifluoromethanesulfonate

98%

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Synonym(s):
Cu(OTf)2, Copper(II) triflate, Cupric trifluoromethanesulfonate, Trifluoromethanesulfonic acid copper(II) salt
Linear Formula:
(CF3SO3)2Cu
CAS Number:
Molecular Weight:
361.68
Beilstein/REAXYS Number:
4028198
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

assay

98%

reaction suitability

core: copper
reagent type: catalyst

mp

≥300 °C

SMILES string

FC(F)(F)S(=O)(=O)O[Cu]OS(=O)(=O)C(F)(F)F

InChI

1S/2CHF3O3S.Cu/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2

InChI key

SBTSVTLGWRLWOD-UHFFFAOYSA-L

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This Item
685038407240734527
Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

100

reaction suitability

core: copper, reagent type: catalyst

reaction suitability

core: copper, reagent type: catalyst

reaction suitability

core: copper, reagent type: catalyst

reaction suitability

core: copper, reagent type: catalyst

mp

≥300 °C

mp

-

mp

160 °C (dec.) (lit.)

mp

190-194 °C

Application

Catalyst for:
  • Mannich condensation
  • Annulative amination
  • Friedel-Crafts reaction
  • Henry reaction
  • Hypervalent iodine reagent-mediated preparation of carbazoles
  • Intramolecular oxidative C-N bond formation for the synthesis of carbazoles
Catalyzes the efficient addition of trimethylsilyl cyanide to carbonyl compounds.

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Storage Class

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flash_point_f

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flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Biswarup Chakraborty et al.
Chemistry, an Asian journal, 15(6), 852-859 (2020-02-06)
In the urge of designing noble metal-free and sustainable electrocatalysts for oxygen evolution reaction (OER), herein, a mineral Digenite Cu9 S5 has been prepared from a molecular copper(I) precursor, [{(PyHS)2 CuI (PyHS)}2 ](OTf)2 (1), and utilized as an anode material
Ahmed M Senan et al.
Journal of agricultural and food chemistry, 65(32), 6912-6918 (2017-07-19)
Utilization of renewable biomass to partly replace the fossil resources in industrial applications has attracted attention due to the limited fossil feedstock with the increased environmental concerns. This work introduced a modified Wacker-type oxidation for transformation of unsaturated fatty acids/esters
Dario Formenti et al.
Chemical reviews, 119(4), 2611-2680 (2018-12-06)
The reduction of nitro compounds to the corresponding amines is one of the most utilized catalytic processes in the fine and bulk chemical industry. The latest development of catalysts with cheap metals like Fe, Co, Ni, and Cu has led
Saravanan, P. et al.
Tetrahedron Letters, 39, 3823-3823 (1998)
Nicole W G Smits et al.
Inorganic chemistry, 58(19), 13007-13019 (2019-09-25)
The structure of the copper complex of the 6-((1-butanethiol)oxy)-tris(2-pyridylmethyl)amine ligand (Cu-tmpa-O(CH2)4SH) anchored to a gold surface has been investigated. To enable covalent attachment of the complex to the gold surface, a heteromolecular self-assembled monolayer (SAM) of butanethiol and a thiol-substituted

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