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680982

Sigma-Aldrich

Cyclopropylzinc bromide solution

0.5 M in THF

Synonym(s):

Bromocyclopropylzinc, Cyclopropane, zinc complex, Cyclopropylzinc(II) bromide

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About This Item

Empirical Formula (Hill Notation):
C3H5BrZn
CAS Number:
126403-68-7
Molecular Weight:
186.37
MDL number:
MFCD08741505
UNSPSC Code:
12352103
PubChem Substance ID:
329760740
NACRES:
NA.22

concentration

0.5 M in THF

density

0.969 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Br[Zn]C1CC1

InChI

1S/C3H5.BrH.Zn/c1-2-3-1;;/h1H,2-3H2;1H;/q;;+1/p-1

InChI key

DUXRKEPSNWXJGV-UHFFFAOYSA-M

Application

Active nucleophile in Pd-catalyzed cross-coupling of heteroaryl halides.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 3

flash_point_f

1.4 °F - closed cup

flash_point_c

-17 °C - closed cup

Certificates of Analysis (COA)

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Campbell, J. B. et al.
Synthetic Communications, 19, 2265-2265 (1989)

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