497517

Benzylzinc bromide solution

0.5 M in THF

• Synonym(s): Benzylbromozinc, Benzylzinc(II) bromide, Bromo(phenylmethyl)zinc
• Linear Formula: C₆H₅CH₂ZnBr
• CAS Number: 62673-31-8
• Molecular Weight: 236.42
• MDL number: MFCD00671803
• UNSPSC Code: 12352103
• PubChem Substance ID: 24873123
• NACRES: NA.22

Properties

• concentration: 0.5 M in THF
• density: 0.978 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: Br[Zn]Cc1ccccc1
• InChI: 1S/C7H7.BrH.Zn/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1
• InChI key: OQPRTUBCROVGHA-UHFFFAOYSA-M

Description

Application

Benzylzinc bromide solution can be used as a nucleophile for the Mannich-type synthesis of 1,2-diarylethylpiperazines. It can also undergo C−C cross coupling reactions with aryl halides.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Safety Information

• pictograms: GHS02,GHS08,GHS07
• signalword: Danger
• hcodes: H225,H302,H319,H335,H351
• pcodes: P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• target_organs: Respiratory system
• supp_hazards: EUH019
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 1.0 °F - closed cup
• flash_point_c: -17.22 °C - closed cup