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About This Item
Empirical Formula (Hill Notation):
C17H19ClN2
CAS Number:
Molecular Weight:
286.80
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
Product Name
2-Mesityl-5-methylimidazo[1,5-a]pyridinium chloride, 97%
Quality Level
assay
97%
form
solid
reaction suitability
reagent type: catalyst
mp
>300 °C
SMILES string
[Cl-].Cc1cc(C)c(c(C)c1)-[n+]2cc3cccc(C)n3c2
InChI
1S/C17H19N2.ClH/c1-12-8-13(2)17(14(3)9-12)18-10-16-7-5-6-15(4)19(16)11-18;/h5-11H,1-4H3;1H/q+1;/p-1
InChI key
DJFXURXZOPNPGY-UHFFFAOYSA-M
Related Categories
Application
Reactant for gold cycloisomerization catalytic reactions
Stable N-heterocyclic carbene precursor.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Manuel Alcarazo et al.
Journal of the American Chemical Society, 127(10), 3290-3291 (2005-03-10)
The imidazo[1,5-a]pyridine skeleton provides a versatile platform for the generation of new types of stable N-heterocyclic carbenes. Rh(I) mono- (6) and biscarbenes (7) from imidazo[1,5-a]pyridin-3-ylidenes (ImPy) and derivatives such as 13 from a mesoionic carbene were synthesized and characterized.
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