710326

(1,3-Dioxolan-2-ylmethyl)zinc bromide

0.6 M in THF

• Empirical Formula (Hill Notation): C₄H₇BrO₂Zn
• Molecular Weight: 232.39
• NACRES: NA.22
• PubChem Substance ID: 329762915
• UNSPSC Code: 12352005
• MDL number: MFCD07698709
• Form: liquid

Properties

• form: liquid
• Quality Segment: 100
• reaction suitability: reaction type: C-C Bond Formation
• concentration: 0.6 M in THF
• density: 0.992 g/mL at 25 °C
• functional group: ether
• storage temp.: 2-8°C
• SMILES string: Br[Zn]CC1OCCO1
• InChI: 1S/C4H7O2.BrH.Zn/c1-4-5-2-3-6-4;;/h4H,1-3H2;1H;/q;;+1/p-1
• InChI key: LOJRLQRGBKTHDB-UHFFFAOYSA-M

Description

General description

(1,3-Dioxolan-2-ylmethyl)zinc bromide is an organozinc compound used as a reagent in Negishi cross-coupling reaction to prepare aryl or heteroaryl scaffolds via C-C bond formation.

Application

(1,3-Dioxolan-2-ylmethyl)zinc bromide can be used as a reagent in the allylic alkylation reactions in the presence of iridium catalyst.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Safety Information

• pictograms: GHS02,GHS08,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H302,H315,H318,H335,H336,H351
• pcodes: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Central nervous system, Respiratory system
• supp_hazards: EUH019
• Storage Class: 3 - Flammable liquids
• flash_point_f: -22.0 °F
• flash_point_c: -30 °C