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Sigma-Aldrich

1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

≥98.5% (HPLC)

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Synonym(s):
AMIMTFSI
Empirical Formula (Hill Notation):
C9H11F6N3O4S2
CAS Number:
Molecular Weight:
403.32
MDL number:
PubChem Substance ID:
NACRES:
NA.22

assay

≥98.5% (HPLC)

form

liquid

impurities

≤1% water

SMILES string

C[n+]1ccn(CC=C)c1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C7H11N2.C2F6NO4S2/c1-3-4-9-6-5-8(2)7-9;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h3,5-7H,1,4H2,2H3;/q+1;-1

InChI key

DHMWATGUEVQTIY-UHFFFAOYSA-N

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This Item
7277094396177896
Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

form

liquid

form

liquid

form

crystals

form

liquid

impurities

≤1% water

impurities

≤1.0% water

impurities

-

impurities

≤0.5% water

General description

1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide is an ionic liquid that can be prepared by reacting 1-allyl-3-methylimidazolium chloride and lithium bis(trifluoromethylsulfonyl)imide under microwave conditions.

Application

1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide can be used to prepare AMIMTFSI-propylene carbonate based electrolyte, with potential application in lithium-ion batteries. It also finds application in alkanes/alkenes separation process. AMIMTFSI can be used as a surface protector to develop luminescent silicon nanoparticles.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Thermodynamics and selectivity of separation based on activity coefficients at infinite dilution of various solutes in 1-allyl-3-methylimidazolium bis {(trifluoromethyl) sulfonyl} imide ionic liquid.
Wlazlo M, et al.
The Journal of Chemical Thermodynamics, 102, 39-47 (2016)
Hassan M Albishri et al.
Talanta, 200, 107-114 (2019-05-01)
Acetylcholine (ACh) and its precursor choline (Ch) play important roles in many biological processes. It is expected that Alzheimer's disease is occurred due to the reduction in synthesis of ACh. On the other hand, the increase in the level of
(Liquid+ liquid) equilibrium for the ternary systems {heptane+ toluene+ 1-allyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide} and {heptane+ toluene+ 1-methyl-3-propylimidazolium bis (trifluoromethylsulfonyl) imide} ionic liquids
Garcia, Silvia, et al.
The Journal of Chemical Thermodynamics, 43.11, 1641-1645 (2011)
Liquid?liquid equilibrium data for {heptane+ aromatic+ 1-(2-hydroxyethyl)-3-methylimidazolium bis (trifluoromethylsulfonyl) imide ([hemim][NTf2])} ternary systems
Ebrahimi, M., et al.
Journal of Chemical and Engineering Data, 59.2, 197-204 (2014)
Synthesis and properties of pyrrolidinium and piperidinium bis (trifluoromethanesulfonyl) imide ionic liquids with allyl substituents
Yim, Tae Eun, et al.
J. Korean Chem. Soc., 28.9, 1567-1567 (2007)

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