1.05423

Ammonia solution

28-30%, for analysis EMSURE^® ACS,Reag. Ph Eur

• Synonym(s): Ammonium hydroxide solution, Ammonia water, Ammonium hydroxide solution, Ammonia aqueous, Ammonia water
• Linear Formula: NH₄OH
• CAS Number: 1336-21-6
• Molecular Weight: 35.05
• Beilstein/REAXYS Number: 3587154
• MDL number: MFCD00066650
• UNSPSC Code: 12352402
• NACRES: NA.21

Properties

• product name: Ammonia solution 28-30%, for analysis EMSURE^® ACS,Reag. Ph Eur
• grade: ACS reagent
• Quality Level: 300
• agency: reag. Ph. Eur.
• vapor pressure: 635 hPa ( 20 °C)
• product line: EMSURE^®
• form: liquid
• expl. lim.: 27 %
• concentration: 28.0-30.0% NH₄OH
• impurities: ≤0.020 ppm Ag (Silver); ≤0.020 ppm Ga (Gallium); ≤0.020 ppm In (Indium); ≤0.020 ppm Li (Lithium); ≤0.050 ppm Ba (Barium); ≤0.050 ppm Cd (Cadmium); ≤0.050 ppm Co (Cobalt); ≤0.050 ppm Cr (Chromium); ≤0.050 ppm Mn (Manganese); ≤0.050 ppm Mo (Molybdenum); ≤0.050 ppm Ni (Nickel); ≤0.050 ppm Pb (Lead); ≤0.050 ppm Tl (Thallium); ≤0.100 ppm Au (Gold); ≤0.100 ppm Bi (Bismuth); ≤0.100 ppm Cu (Copper); ≤0.100 ppm Fe (Iron); ≤0.100 ppm Mg (Magnesium); ≤0.100 ppm Pt (Platinum); ≤0.100 ppm Sn (Tin); ≤0.100 ppm Sr (Strontium); ≤0.100 ppm Ti (Titanium); ≤0.100 ppm Zn (Zinc); ≤0.2 ppm Sulphide (S); ≤0.3 ppm Chloride (Cl); ≤0.5 ppm Heavy metals (as Pb); ≤0.5 ppm Phosphate (PO₄); ≤0.500 ppm Al (Aluminium); ≤0.500 ppm As (Arsenic); ≤0.500 ppm Ca (Calcium); ≤0.500 ppm K (Potassium); ≤0.500 ppm Na (Sodium); ≤10 ppm Carbonate (as CO₂); ≤10 ppm Non volatile matter; ≤2 ppm Nitrate (NO₃); ≤2 ppm Pyridine and related substances; ≤2 ppm Sulphate (SO₄); ≤5 ppm Silicate (as SiO₂); ≤5 ppm Substances reducing potassium permanganate
• SMILES string: [NH4+].[OH-]
• ign. residue: ≤10 ppm
• pH: >12 (20 °C in H₂O, strongly alkaline)
• bp: 32 °C
• mp: -72 °C
• density: 0.9 g/mL at 25 °C (lit.); 0.892-0.910 (relative density (d 20/20))
• storage temp.: 2-30°C
• InChI: 1S/H3N.H2O/h1H3;1H2
• InChI key: VHUUQVKOLVNVRT-UHFFFAOYSA-N

Description

Packaging

Due to quality and safety aspects Ammonia Solution will no longer be offered in glass bottles but solely in HDPE bottles.

Please note the following replacements:
1054231000 (1 L glass bottle) replaced by 1054231011 (1 L HDPE bottle)
1054232500 (2.5 L glass bottle) replaced by 1054232511 (2.5 L HDPE bottle)

More information about our ergonomic and unbreakable HDPE bottles can be found here: www.SigmaAldrich.com/hdpe-bottle

Analysis Note

Assay (acidimetric, NH₃): 28.0 - 30.0 %
Identity: passes test
Appearance: passes test
Appearance of solution: passes test
Relative Density (d 20/20): 0.892 - 0.910
Carbonate (as CO₂): ≤ 10 ppm
Chloride (Cl): ≤ 0.3 ppm
Nitrate (NO₃): ≤ 2 ppm
Phosphate (PO₄): ≤ 0.5 ppm
Heavy metals (as Pb): ≤ 0.5 ppm
Silicate (as SiO₂): ≤ 5 ppm
Sulphate (SO₄): ≤ 2 ppm
Sulphide (S): ≤ 0.2 ppm
Ag (Silver): ≤ 0.020 ppm
Al (Aluminium): ≤ 0.500 ppm
As (Arsenic): ≤ 0.500 ppm
Au (Gold): ≤ 0.100 ppm
Ba (Barium): ≤ 0.050 ppm
Bi (Bismuth): ≤ 0.100 ppm
Ca (Calcium): ≤ 0.500 ppm
Cd (Cadmium): ≤ 0.050 ppm
Co (Cobalt): ≤ 0.050 ppm
Cr (Chromium): ≤ 0.050 ppm
Cu (Copper): ≤ 0.100 ppm
Fe (Iron): ≤ 0.100 ppm
Ga (Gallium): ≤ 0.020 ppm
In (Indium): ≤ 0.020 ppm
K (Potassium): ≤ 0.500 ppm
Li (Lithium): ≤ 0.020 ppm
Mg (Magnesium): ≤ 0.100 ppm
Mn (Manganese): ≤ 0.050 ppm
Mo (Molybdenum): ≤ 0.050 ppm
Na (Sodium): ≤ 0.500 ppm
Ni (Nickel): ≤ 0.050 ppm
Pb (Lead): ≤ 0.050 ppm
Pt (Platinum): ≤ 0.100 ppm
Sn (Tin): ≤ 0.100 ppm
Sr (Strontium): ≤ 0.100 ppm
Ti (Titanium): ≤ 0.100 ppm
Tl (Thallium): ≤ 0.050 ppm
Zn (Zinc): ≤ 0.100 ppm
Pyridine and related substances: ≤ 2 ppm
Substances Reducing Permanganate (ACS): passes test
Substances reducing potassium permanganate: ≤ 5 ppm
Residue after ignition: ≤ 10 ppm
Non volatile matter: ≤ 10 ppm

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• pictograms: GHS05,GHS07,GHS09
• signalword: Danger
• hcodes: H314 - H335 - H410
• pcodes: P261 - P271 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 8B - Non-combustible, corrosive hazardous materials
• wgk_germany: WGK 2
• flash_point_f: Not applicable
• flash_point_c: Not applicable