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Key Documents

06561

Sigma-Aldrich

Formic acid triethylamine complex 5:2

≥99.0% (NT)

Synonym(s):

Triethylammonium formate 2:5

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About This Item

Linear Formula:
5HCOOH · 2N(CH2CH3)3
CAS Number:
Molecular Weight:
86.50
Beilstein/REAXYS Number:
4150472
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

≥99.0% (NT)

refractive index

n20/D 1.428

SMILES string

OC=O.OC=O.OC=O.OC=O.OC=O.CCN(CC)CC.CCN(CC)CC

InChI

1S/2C6H15N.5CH2O2/c2*1-4-7(5-2)6-3;5*2-1-3/h2*4-6H2,1-3H3;5*1H,(H,2,3)

InChI key

NLOIHFJXBNFDSF-UHFFFAOYSA-N

Application

Reductant for iridium-catalyzed greener amine synthesis by transfer hydrogenation of imines.

A Versatile Catalyst for Reductive Amination by Transfer Hydrogenation

Other Notes

Activated form of formic acid used for reduction reactions

Pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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K. Wagner
Angewandte Chemie (International Edition in English), 82, 73-73 (1970)

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