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Sigma-Aldrich

1-Hexyl-3-methylimidazolium hexafluorophosphate

≥97.0% (HPLC)

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Synonym(s):
HMIMPF6
Empirical Formula (Hill Notation):
C10H19F6N2P
CAS Number:
Molecular Weight:
312.24
Beilstein/REAXYS Number:
8955409
MDL number:
PubChem Substance ID:
NACRES:
NA.22

description

electrochemical window 5.5 V

Quality Level

assay

≥97.0% (HPLC)

form

liquid

refractive index

n20/D 1.419

SMILES string

F[P-](F)(F)(F)(F)F.CCCCCCn1cc[n+](C)c1

InChI

1S/C10H19N2.F6P/c1-3-4-5-6-7-12-9-8-11(2)10-12;1-7(2,3,4,5)6/h8-10H,3-7H2,1-2H3;/q+1;-1

InChI key

YPWSSSRXUOQNMQ-UHFFFAOYSA-N

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Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

-

form

liquid

form

liquid

form

-

form

solid

refractive index

n20/D 1.419

refractive index

n20/D 1.411 (lit.)

refractive index

n20/D 1.41

refractive index

-

description

electrochemical window 5.5 V

description

-

description

-

description

-

General description

1-Hexyl-3-methylimidazolium hexafluorophosphate is a water-immiscible imidazolium-type room temperature ionic liquid (RTIL) suitable for electrochemistry.
https://www.sigmaaldrich.com/content/dam/sigma-aldrich/materials-science/material-matters/material_matters_v4n4.pdf#page=18

application

HMIMPF6 can be used as a chelate extraction solvent for divalent metal cations using 4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedione (thenoyltrifluoroacetone, Htta) as an extractant.

Other Notes

Ionic liquid employed in Friedel-Crafts alkylation of aromatic compounds; polarity of salt.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Arezou Taghvimi et al.
Journal of separation science, 42(2), 582-590 (2018-11-11)
Ionic liquid carbon-coated magnetic nanoparticles were successfully applied as an adsorbent in a mixed hemimicelle magnetic dispersive solid-phase extraction method for the determination of tramadol from urine samples coupled with high-performance liquid chromatography with UV-vis detection. The significant parameters affect
Use of 1-alkyl-3-methylimidazolium hexafluorophosphate room temperature ionic liquids as chelate extraction solvent with 4, 4, 4-trifluoro-1-(2-thienyl)-1, 3-butanedione.
Hirayama N, et al.
Talanta, 65(1), 255-260 (2005)
High-pressure phase behavior of systems with ionic liquids: Part IV. Binary system carbon dioxide+ 1-hexyl-3-methylimidazolium tetrafluoroborate
Costantini, Marco, et al.
Journal of Chemical and Engineering Data, 50.1, 52-55 (2005)
Activity coefficients at infinite dilution of organic solutes in 1-hexyl-3-methylimidazolium hexafluorophosphate from gas? liquid chromatography
Letcher, Trevor M., et al.
Journal of Chemical and Engineering Data, 48.3, 708-711 (2003)
C.E. Song et al.
Chemical Communications (Cambridge, England), 1695-1695 (2000)

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