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71853

Sigma-Aldrich

Sodium perchlorate monohydrate

puriss. p.a., ACS reagent, ≥98.0% (T)

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About This Item

Linear Formula:
NaClO4 · H2O
CAS Number:
Molecular Weight:
140.46
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

grade

ACS reagent
puriss. p.a.

assay

≥98.0% (T)

form

powder, crystals or chunks

impurities

≤0.0005% total nitrogen (N)

pH

6.0-8.0 (25 °C, 50 mg/mL in H2O)

anion traces

chloride (Cl-): ≤30 mg/kg
sulfate (SO42-): ≤20 mg/kg

cation traces

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤3 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg
heavy metals: ≤5 ppm (by ICP-OES)

SMILES string

O.[Na+].[O-]Cl(=O)(=O)=O

InChI

1S/ClHO4.Na.H2O/c2-1(3,4)5;;/h(H,2,3,4,5);;1H2/q;+1;/p-1

InChI key

IXGNPUSUVRTQGW-UHFFFAOYSA-M

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General description

Sodium perchlorate monohydrate (NaClO4· H2O) is a hydrated sodium salt. Its crystal structure has been investigated by three-dimensional single crystal x-ray diffraction studies. Its crystals belong to the monoclinic crystal system having space group C2/c.

Application

Sodium perchlorate monohydrate (NaClO4· H2O) may be used in the preparation of 0.01M NaClO4 solution. This solution was employed in oxalate adsorption isotherm experiments.
Sodium perchlorate monohydrate has been used as a component of ion exchange (IE) buffer A and B for the purification of RNA using IE-high-performance liquid chromatography (HPLC).

pictograms

Flame over circleExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 1

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

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Hydrogen bond studies. CII. An X-ray determination of the crystal structure of sodium perchlorate monohydrate, NaClO4. H2O.
Berglund B, et al.
Acta Crystallographica Section B, Structural Science, 31(7), 1842-1846 (1975)
Dissolution mechanisms of goethite in the presence of siderophores and organic acids.
Reichard PU, et al.
Geochimica et Cosmochimica Acta, 71(23), 5635-5650 (2007)
Deniz Ucar et al.
Environmental technology, 37(2), 183-191 (2015-06-24)
Nitrate and perchlorate were identified as significant water contaminants all over the world. This study aims at evaluating the performances of the heterotrophic-autotrophic sequential denitrification process for reductive nitrate and perchlorate removal from drinking water. The reduced nitrate concentration in
Christopher Polonyi et al.
Dalton transactions (Cambridge, England : 2003), 43(31), 11941-11949 (2014-06-27)
The ability of the anticancer active drug cisplatin to exert biological activity through interference with nucleic acid function is well documented. Since kinetics play a key role in determining product distributions in these systems, methods for accurate documentation of reactivity
Ana Vemić et al.
Journal of pharmaceutical and biomedical analysis, 102, 314-320 (2014-12-03)
The aim of this paper is to present a development of liquid chromatographic method when chaotropic salts are used as mobile phase additives following the QbD principles. The effect of critical process parameters (column chemistry, salt nature and concentration, acetonitrile

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