52985

cis-3-Hexene

≥95.0%

• 実験式（ヒル表記法）: C₆H₁₂
• CAS番号: 7642-09-3
• 分子量: 84.16
• Beilstein: 1718858
• MDL番号: MFCD00085300
• UNSPSCコード: 12352100
• PubChem Substance ID: 57651395
• NACRES: NA.22
• アッセイ: ≥95.0%

特性

• 品質水準: 100
• アッセイ: ≥95.0%
• 屈折率: n20/D 1.395
• bp: 66-68 °C (lit.)
• 密度: 0.681 g/mL at 20 °C (lit.)
• SMILES記法: CC\C=C/CC
• InChI: 1S/C6H12/c1-3-5-6-4-2/h5-6H,3-4H2,1-2H3/b6-5-
• InChI Key: ZQDPJFUHLCOCRG-WAYWQWQTSA-N

詳細

詳細

cis-3-Hexene is a symmetrical cis-disubstituted alkene that can be prepared by the hydroboration of 3-hexyne followed by protonolysis. The gas-phase study of its molecular structure by electron diffraction combined with molecular mechanical calculations reveals the presence of the (+ac, +ac) and the (-ac, +ac) forms. cis-3-Hexene undergoes epoxidation with dimethyldioxirane to form the corresponding epoxide.

アプリケーション

cis-3-Hexene may be used in the preparation of 3-hexanol via asymmetric hydroboration with diisopinocampheylborane (Ipc₂BH).

安全性情報

• ピクトグラム: GHS02,GHS08,GHS07
• シグナルワード: Danger
• 危険有害性情報: H225,H304,H319
• 注意書き: P210 - P233 - P240 - P301 + P310 - P305 + P351 + P338 - P331
• 危険有害性の分類: Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 2
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 3
• 引火点(°F): -13.0 °F - closed cup
• 引火点(℃): -25 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter