565849

4-(トリフルオロメチル)ベンゼンスルホニルクロリド

97%

• 別名: α,α,α-Trifluoro-p-toluenesulfonyl chloride, 4-(Trifluoromethyl)benzene-1-sulfonyl chloride, [4-(Trifluoromethyl)phenyl]sulfonyl chloride, [p-(Trifluoromethyl)phenyl]sulfonyl chloride, p-Trifluoromethylbenzenesulfonyl chloride
• 化学式: CF₃C₆H₄SO₂Cl
• CAS番号: 2991-42-6
• 分子量: 244.62
• Beilstein: 2113604
• MDL番号: MFCD00042422
• UNSPSCコード: 12352100
• PubChem Substance ID: 24880261
• NACRES: NA.22
• アッセイ: 97%

特性

• 品質水準: 100
• アッセイ: 97%
• mp: 30-34 °C (lit.)
• 官能基: fluoro
• SMILES記法: FC(F)(F)c1ccc(cc1)S(Cl)(=O)=O
• InChI: 1S/C7H4ClF3O2S/c8-14(12,13)6-3-1-5(2-4-6)7(9,10)11/h1-4H
• InChI Key: OZDCZHDOIBUGAJ-UHFFFAOYSA-N

詳細

アプリケーション

4-(Trifluoromethyl)benzenesulfonyl chloride may be used to synthesize β-arylated thiophenes and 2,5-diarylated pyrrolevia palladium catalyzed desulfitative arylation of thiophenes and pyrroles, respectively.
4-(Trifluoromethyl)benzenesulfonyl chloride and N-vinylpyrrolidinone in acetonitrile can undergo photo-irradiation with visible light in the presence of Ir(ppy)₂(dtbbpy)PF₆ ([4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[2-(2-pyridinyl-N)phenyl-C]iridium(III)hexafluorophosphate) and disodium phosphate to give the corresponding E-vinyl sulfone.

注意

低融点の固体。

安全性情報

• ピクトグラム: GHS05
• シグナルワード: Danger
• 危険有害性情報: H314
• 注意書き: P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
• 危険有害性の分類: Skin Corr. 1B
• 補足的ハザード: EUH014
• 保管分類コード: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• 引火点(°F): >230.0 °F
• 引火点(℃): > 110 °C
• 個人用保護具 (PPE): Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter