775118

ボランジメチルスルフィド錯体 溶液

1.0 M in 2-methyltetrahydrofuran

• 別名: BMS, トリヒドロ[チオビス[メタン]]ボロン
• 化学式: (CH₃)₂S · BH₃
• CAS番号: 13292-87-0
• 分子量: 75.97
• Beilstein: 3663489
• MDL番号: MFCD00013189
• UNSPSCコード: 12352112
• PubChem Substance ID: 329767736
• NACRES: NA.22

特性

• 形状: liquid
• 品質水準: 100
• 反応適合性: reagent type: reductant
• 環境により配慮した代替製品の特徴: Safer Solvents and Auxiliaries; Use of Renewable Feedstocks; Inherently Safer Chemistry for Accident Prevention; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 濃度: 1.0 M in 2-methyltetrahydrofuran
• 密度: 0.844 g/mL at 25 °C
• 官能基: thioether
• 環境により配慮した代替製品カテゴリ: , Aligned
• 保管温度: 2-8°C
• SMILES記法: B.CSC
• InChI: 1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3
• InChI Key: RMHDLBZYPISZOI-UHFFFAOYSA-N

詳細

詳細

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks" and "Inherently Safer Chemistry for Accident Prevention". Find details here.

アプリケーション

位置選択的還元剤として使用される反応

反応物は、下記に関連します:

• ヒドロキシアミドホウ素化 / 酸化

かご状化合物の合成

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Commonly used in hydroboration of olefins and as a reductant of carbonyls. 2-Me-THF has shown potential as an environmentally friendly solvent compared to commonly used solvents; e.g. dichloromethane and THF.

For an alternative to Tetrahydrofuran and Dichloromethane, please see: An alternative to Tetrahydrofuran and Dichloromethane

包装

The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

法的情報

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

安全性情報

• ピクトグラム: GHS02,GHS08,GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H225,H260,H302,H315,H318,H360FD
• 注意書き: P210 - P231 + P232 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• 危険有害性の分類: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Skin Irrit. 2 - Water-react 1
• 補足的ハザード: EUH019
• 保管分類コード: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 2
• 引火点(°F): 9.3 °F
• 引火点(℃): -12.6 °C