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Merck

931578

Sigma-Aldrich

塩化ルテニウム(III) 水和物

≥99.9% trace metals basis

別名:

三塩化ルテニウム

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About This Item

化学式:
RuCl3 · xH2O
CAS番号:
分子量:
207.43 (anhydrous basis)
MDL番号:
UNSPSCコード:
12352302
NACRES:
NA.21

品質水準

アッセイ

≥99.9% trace metals basis

形状

powder

不純物

≤1000.0 ppm (trace metals analysis)

溶解性

acetone: soluble ((lit.))
ethanol: soluble
water: soluble

密度

3.11 g/cm3

SMILES記法

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

InChI Key

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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詳細

Ruthenium chloride hydrate is a dark brown or black solid often used as a powder. The hydrate is hygroscopic and is soluble in water, ethanol, acetone, and a wide range of polar organic solvents. The anhydrous form is insoluble.
Industrially, ruthenium trichloride hydrate is produced by dissolving ruthenium oxides in hydrochloric acid. The hydrated salt is obtained by recrystallization.

アプリケーション

Ruthenium chloride is most used as a precursor for the synthesis of ruthenium complexes. Our RuCl3·H2O with 99.9% trace metals purity is well-suited for applications in materials science. One common application of ruthenium trichloride hydrate is in the synthesis of ruthenium nanoparticles, which are used as catalysts or composited with other materials and used as co-catalysts for both oxygen and hydrogen evolution reactions. Researchers have used our ruthenium chloride hydrate to produce high-quality, catalytically active ruthenium nanoparticles and ruthenium oxide nanoparticles.
Another common application of ruthenium chloride hydrate is as a precursor for single-atom catalysts. For example, scientists have used ruthenium chloride hydrate for the synthesis of ruthenium single-atom-doped ZrO2 particles to catalyze nitrogen fixation and for the synthesis of ruthenium single-atom-doped MXenes to catalyze hydrogen evolution. A third common application of ruthenium chloride hydrate is in the synthesis of metal alloys, like PtRuIr, or PtRuFe, which are investigated for electrocatalysis, usually the oxidation of simple organics like methanol or formic acid.
For use in all these applications, also consider our higher-purity ruthenium chloride hydrate, 463779, with trace metals purity greater than 99.98%, which offers the best reproducibility and purity.

ピクトグラム

CorrosionExclamation markEnvironment

シグナルワード

Danger

危険有害性情報

危険有害性の分類

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

保管分類コード

8A - Combustible corrosive hazardous materials

WGK

WGK 3

引火点(°F)

Not applicable

引火点(℃)

Not applicable


適用法令

試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。

Jan Code

931578-BULK:
931578-10G:
931578-VAR:
931578-2G:


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文書ライブラリにアクセスする

Nitrogen Fixation by Ru Single-Atom Electrocatalytic Reduction
Tao, H., Choi, C., et al.
Chem, 5, 204-214 (2019)
Synthesis and Activities of Rutile IrO2 and RuO2 Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions
Lee, Y., Suntivich, J., et al.
The Journal of Physical Chemistry Letters, 3, 399?404-399?404 (2012)
High Performance PtRuIr Catalysts Supported on Carbon Nanotubes for the Anodic Oxidation of Methanol
Liao, S., Holmes, K.A., et al.
Journal of the American Chemical Society, 128, 3504-3505 (2006)
Heteroatom-Mediated Interactions between Ruthenium Single Atoms and an MXene Support for Efficient Hydrogen Evolution
Ramalingam, V., et al.
Advanced Materials, 31, e1903841-e1903841 (2019)
Fabing Su et al.
Journal of the American Chemical Society, 129(46), 14213-14223 (2007-11-02)
We report here a thermal reduction method for preparing Ru catalysts supported on a carbon substrate. Mesoporous SBA-15 silica, surface-carbon-coated SBA-15, templated mesoporous carbon, activated carbon, and carbon black with different pore structures and compositions were employed as catalyst supports

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