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Merck
모든 사진(2)

주요 문서

241431

Sigma-Aldrich

Tungsten hexacarbonyl

97%

동의어(들):

Hexacarbonyltungsten, Tungsten carbonyl

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About This Item

Linear Formula:
W(CO)6
CAS Number:
Molecular Weight:
351.90
EC Number:
MDL number:
UNSPSC 코드:
12352103
PubChem Substance ID:
NACRES:
NA.23

vapor density

12.1 (vs air)

Quality Level

vapor pressure

1.2 mmHg ( 67 °C)

분석

97%

형태

solid

반응 적합성

core: tungsten
reagent type: catalyst

불순물

<1% Mo

mp

150 °C (lit.)

density

2.65 g/mL at 25 °C (lit.)

SMILES string

[W].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/6CO.W/c6*1-2;

InChI key

FQNHWXHRAUXLFU-UHFFFAOYSA-N

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애플리케이션

Precursor to a Fischer carbene complex which reduces Pd(II) to nanoparticulate Pd(0) that is catalytically active in Hiyama cross-coupling.
Tungsten hexacarbonyl, [W(CO)6] may be used as a precursor for the deposition of WO3-x films, which may be used as gas sensors for the detection of NO2.

픽토그램

Skull and crossbones

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type N95 (US)


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문서 라이브러리 방문

이미 열람한 고객

Dipankar Srimani et al.
Organic letters, 9(18), 3639-3642 (2007-08-07)
An efficient synthesis of Pd nanoparticles in water has been developed using a Fischer carbene complex of tungsten as the reductant and PEG as the capping agent. The colloidal palladium (1 mol %) efficiently catalyzes Hiyama cross-coupling reactions performed in
Aerosol assisted chemical vapour deposition of WO 3 thin films from tungsten hexacarbonyl and their gas sensing properties.
Ashraf S, et al.
Journal of Materials Chemistry, 17.35, 3708-3713 (2007)
Seth M Dumbris et al.
The Journal of organic chemistry, 74(22), 8862-8865 (2009-10-30)
Hydantoins can be synthesized from the corresponding amino amides employing oxidative catalytic carbonylation using W(CO)(6) as the catalyst, I(2) as the oxidant, CO as the carbonyl source, and DBU as base. Secondary amides afford the hydantoins in good to excellent
Lei Li et al.
Journal of the American Society for Mass Spectrometry, 15(1), 87-102 (2003-12-31)
The internal energy distributions, P(epsilon), of a millisecond pulsed radio frequency glow discharge plasma were investigated using tungsten hexcarbonyl W(CO)(6) as a "thermometer molecule". Vapor of the probe molecule, W(CO)(6), was introduced into the plasma and subjected to various ionization
F Porrati et al.
Nanotechnology, 20(19), 195301-195301 (2009-05-08)
W-based granular metals have been prepared by electron-beam-induced deposition from the tungsten hexacarbonyl W(CO)(6) precursor. In situ electrical conductivity measurements have been performed to monitor the growth process and to investigate the behavior of the deposit under electron beam post-irradiation

문서

The properties of many devices are limited by the intrinsic properties of the materials that compose them.

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