327638
Bromopentacarbonylrhenium(I)
98%
동의어(들):
Pentacarbonylbromorhenium, Pentacarbonylrhenium bromide, Rhenium(I) pentacarbonyl bromide
로그인조직 및 계약 가격 보기
모든 사진(2)
About This Item
Linear Formula:
Re(CO)5Br
CAS Number:
Molecular Weight:
406.16
EC Number:
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22
가격 및 재고 정보를 현재 이용할 수 없음
추천 제품
분석
98%
반응 적합성
core: rhenium
reagent type: catalyst
SMILES string
Br[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI
1S/5CO.BrH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
InChI key
NWJBOTGGBYFKEJ-UHFFFAOYSA-M
애플리케이션
Starting material for rhenium-polypyridine complexes that have potential applications in catalysis and solar energy conversion.
Used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
이미 열람한 고객
Nishiyama, Y.; Kakushou, F. et al.
Bulletin of the Chemical Society of Japan, 73, 2779-2779 (2000)
Ruimao Hua et al.
The Journal of organic chemistry, 69(17), 5782-5784 (2004-08-17)
The addition of carboxylic acids to terminal alkynes is efficiently catalyzed by the early transition-metal complex Re(CO)5Br in toluene or n-heptane at 110 degrees C in an air atmosphere, affording the anti-Markovnikov adducts in good yields with high selectivity. In
Jia-Li Jiang et al.
The Journal of organic chemistry, 70(1), 381-383 (2004-12-31)
In the presence of a catalytic amount of Re(CO)(5)Br, the coupling of epoxides with supercritical CO(2) without an organic solvent at 110 degrees C has afforded cyclic carbonates in good to excellent yields.
Inorganic Chemistry, 29, 2909-2909 (1990)
Tomás F Beltrán et al.
Dalton transactions (Cambridge, England : 2003), 46(28), 9036-9048 (2017-07-01)
The superbulky N-heterocyclic carbenes (NHCs) 2,6-bis(diphenylmethyl)-4-methylimidazol-2-ylidene (IDip*Me) and its 4-methoxy analogue (IDip*OMe) reacted instantaneously with carbon disulfide to afford the corresponding imidazolium-2-dithiocarboxylate zwitterions in high yields. These new dithiolate ligands were fully characterized and their coordination chemistry toward common Re(i)
자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..
고객지원팀으로 연락바랍니다.
