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Merck
모든 사진(1)

주요 문서

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331880

Sigma-Aldrich

(1S,2R)-(+)-2-Amino-1,2-diphenylethanol

99%

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모든 사진(1)

About This Item

Linear Formula:
C6H5CH(NH2)CH(C6H5)OH
CAS Number:
23364-44-5
Molecular Weight:
213.28
Beilstein:
1212828
MDL number:
MFCD00074959
UNSPSC 코드:
12352116
PubChem Substance ID:
24860005
NACRES:
NA.22

Quality Level

100

분석

99%

형태

solid

광학 활성

[α]25/D +7.0°, c = 0.6 in ethanol

mp

142-144 °C (lit.)

작용기

amine
hydroxyl
phenyl

SMILES string

N[C@@H]([C@@H](O)c1ccccc1)c2ccccc2

InChI

1S/C14H15NO/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14,16H,15H2/t13-,14+/m1/s1

InChI key

GEJJWYZZKKKSEV-KGLIPLIRSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

애플리케이션

(1S,2R)-(+)-2-Amino-1,2-diphenylethanol can be used:
  • To prepare vanadium(V) Schiff base complexes, which are used as catalysts in the oxidation of sulfides and olefins.
  • To prepare chiral selectors, which are immobilized on aminated silica gel, applicable as chiral stationary phase in HPLC.
  • To immobilize on the frame of α-zirconium phosphate to yield layered zirconium phosphonates, which are used in the heterogeneous catalysis.
  • As a chiral auxiliary in the preparation of homopropargylic alcohols from aliphatic and aromatic aldehydes.

픽토그램

Exclamation mark
GHS07

신호어

Warning

유해 및 위험 성명서

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves

가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number
MKCR0564
MKCR8922
MKCM8476
MKCD5667
MKBZ7001V

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특정 버전이 필요한 경우 로트 번호나 배치 번호로 특정 인증서를 찾을 수 있습니다.

COA 검색

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Zirconium phosphonate immobilized chiral amino alcohol for heterogeneous enantioselective addition of diethylzinc to benzaldehyde
Zheng B, et al.
Catalysis Communications, 8(12), 1923-1928 (2007)
Vanadium (V) complexes with chiral tridentate Schiff base ligands derived from 1S, 2R (+)-2-amino-1, 2-diphenylethanol and with acetohydroxamate co-ligand: Synthesis, characterization and catalytic activity in the oxidation of prochiral sulfides and olefins
Romanowski G, et al.
J. Mol. Catal. A: Chem., 381, 148-160 (2014)
Asymmetric indium-mediated synthesis of homopropargylic alcohols
Hirayama LC, et al.
Tetrahedron Letters, 47(29), 5173-5176 (2006)
Chuan-Qi Yin et al.
Chirality, 21(4), 442-448 (2008-07-26)
A chiral selector was prepared through the reaction between (1S,2R)-(+)-2-amino-1,2-diphenylethanol and phenyl isocyanate. This selector was immobilized on aminated silica gel, respectively, with bifunctional group linkers of 1,4-phenylene diisocyanate, methylene-di-p-phenyl diisocyanate, and terephthaloyl chloride to produce corresponding three chiral stationary
Michael L Berger et al.
Bioorganic & medicinal chemistry, 17(9), 3456-3462 (2009-04-07)
We resolved 1,2-diphenylethylamine (DPEA) into its (S)- and (R)-enantiomer and used them as precursors for synthesis of (S)- and (R)-1-(1,2-diphenylethyl)piperidine, flexible homeomorphs of the NMDA channel blocker MK-801. We also describe the synthesis of the dicyclohexyl analogues of DPEA. These

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