추천 제품
제품명
L-tert-Leucinol, 98%
분석
98%
광학 활성
[α]26/D +37°, c = 1.5 in ethanol
반응 적합성
reaction type: solution phase peptide synthesis
mp
30-34 °C (lit.)
density
0.9 g/mL at 25 °C (lit.)
응용 분야
peptide synthesis
SMILES string
CC(C)(C)[C@H](N)CO
InChI
1S/C6H15NO/c1-6(2,3)5(7)4-8/h5,8H,4,7H2,1-3H3/t5-/m1/s1
InChI key
JBULSURVMXPBNA-RXMQYKEDSA-N
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애플리케이션
Useful amino acid employed in various asymmetric reactions.
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
194.0 °F - closed cup
Flash Point (°C)
90 °C - closed cup
개인 보호 장비
dust mask type N95 (US), Eyeshields, Gloves
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시험 성적서(COA)
Lot/Batch Number
SimplePHOX, a readily available chiral ligand system for iridium-catalyzed asymmetric hydrogenation.
Sebastian P Smidt et al.
Organic letters, 6(12), 2023-2026 (2004-06-05)
[reaction: see text] New Ir-SimplePHOX complexes Ir-6-Ir-9 catalyze the quantitative, highly enantioselective hydrogenation of a range of unfunctionalized and functionalized olefins. Synthesis, catalytic results, and X-ray crystal structures are presented here.
Tetrahedron, 60, 4459-4473 (2004)
Tetrahedron Letters, 45, 5649-5649 (2004)
Heng Wang et al.
Chirality, 27(8), 523-531 (2015-04-25)
A novel pyridineoxazoline (PyOx) containing helical polymer, poly{(-)-(S)-4-tert-butyl-2-[5-(4-tert-butylphenyl)-3-vinylpyridin-2-yl]-oxazoline} (PA), was designed and synthesized to approach the effect of chain conformation on the catalytic property. Its complex with Cu(OTf)(2) , i.e., Cu(II)-PA, was employed to catalyze the homogeneous Diels-Alder (D-A) reaction
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