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Merck
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주요 문서

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532851

Sigma-Aldrich

Methyl 2-iodobenzoate

97%

동의어(들):

Methyl o-iodobenzoate

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모든 사진(1)

About This Item

Linear Formula:
IC6H4CO2CH3
CAS Number:
610-97-9
Molecular Weight:
262.04
EC Number:
210-243-6
MDL number:
MFCD00016351
UNSPSC 코드:
12352100
PubChem Substance ID:
24877921
NACRES:
NA.22
분석:
97%

Quality Level

200

분석

97%

refractive index

n20/D 1.604 (lit.)

bp

149-150 °C/10 mmHg (lit.)

density

1.784 g/mL at 25 °C (lit.)

작용기

ester
iodo

SMILES string

COC(=O)c1ccccc1I

InChI

1S/C8H7IO2/c1-11-8(10)6-4-2-3-5-7(6)9/h2-5H,1H3

InChI key

BXXLTVBTDZXPTN-UHFFFAOYSA-N

일반 설명

Methyl 2-iodobenzoate can be prepared from 2-iodobenzoic acid via esterification. It undergoes cobalt-catalyzed cyclization with aldehydes to form phthalide derivatives. The microbial dihydroxylation of methyl 2-iodobenzoate forms a nonracemic iodocyclohexene carboxylate intermediate. This intermediate forms the precursor for preparing kibdelone C.

애플리케이션

Methyl 2-iodobenzoate may be used in the preparation of:
  • N-substituted 4-methylene-3,4-dihydro-1(2H)-isoquinolin-1-ones
  • methyl diphenylacetylene-2-carboxylate
  • methyl 2-heptynylphenylbenzoate
  • (E)-2-[3-[3-[2-(7-chloro-2-quinolinyl)ethenyl]phenyl]-3-oxopropyl]benzoic acid methyl ester
  • 4-(2-carbomethoxyphenyl)-3-(1-methylethoxy)cyclobut-3-ene-1,2-dione
  • 3-(2-carbomethoxyphenyl)-4-methylcyclobuten-3-ene-1,2-dione 2-(ethylene acetal)

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number
BCCM0725
BCCG5628
BCCB1928
BCBK3405V
BCBH9341V

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

An efficient synthesis of LTD4 antagonist L-699,392.
The Journal of Organic Chemistry, 58(14), 3731-3735 (1993)
3-Stannylcyclobutenediones as nucleophilic cyclobutenedione equivalents. Synthesis of substituted cyclobutenediones and cyclobutenedione monoacetals and the beneficial effect of catalytic copper iodide on the Stille reaction.
Liebeskind LS and Fengl RW.
The Journal of Organic Chemistry, 55(19), 5359-5364 (1990)
Palladium homogeneous and supported catalysis: synthesis of functional acetylenics and cyclisation to heterocycles.
Villemin D and Goussu D.
Heterocycles, 29(7), 1255-1261 (1989)
Highly Efficient Cyclization of o?Iodobenzoates with Aldehydes Catalyzed by Cobalt Bidentate Phosphine Complexes: A Novel Entry to Chiral Phthalides.
Chang HT, et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 13(15), 4356-4363 (2007)
Synthesis of N-substituted 4-methylene-3, 4-dihydro-1 (2H)-isoquinolin-1-ones via a palladium-catalysed three-component process.
Grigg R, et al.
Tetrahedron, 43(14), 2601-2603 (2002)
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