추천 제품
양식
solid
Quality Level
반응 적합성
core: silver
reagent type: catalyst
mp
252-256 °C (lit.)
SMILES string
[Ag+].CS([O-])(=O)=O
InChI
1S/CH4O3S.Ag/c1-5(2,3)4;/h1H3,(H,2,3,4);/q;+1/p-1
InChI key
MLKQJVFHEUORBO-UHFFFAOYSA-M
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애플리케이션
Catalyst for:
- Heterocyclization reactions
- CO2-mediated rearrangement of propargyl alcohols for the synthesis of a,ß-unsaturated ketones and esters
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
dust mask type N95 (US), Eyeshields, Gloves
이미 열람한 고객
Claudio Pettinari et al.
Inorganic chemistry, 50(21), 11173-11183 (2011-10-18)
Five new silver(I) complexes of formulas [Ag(Tpms)] (1), [Ag(Tpms)(PPh(3))] (2), [Ag(Tpms)(PCy(3))] (3), [Ag(PTA)][BF(4)] (4), and [Ag(Tpms)(PTA)] (5) {Tpms = tris(pyrazol-1-yl)methanesulfonate, PPh(3) = triphenylphosphane, PCy(3) = tricyclohexylphosphane, PTA = 1,3,5-triaza-7-phosphaadamantane} have been synthesized and fully characterized by elemental analyses, (1)H, (13)C
Chad E Wujcik et al.
Journal of separation science, 33(6-7), 826-833 (2010-01-21)
Hydrophilic retention coefficients for 17 peptides were calculated based on retention coefficients previously published for TSKgel silica-60 and were compared with the experimental elution profile on a Waters Atlantis HILIC silica column using TFA and methanesulfonic acid (MSA) as ion-pairing
Eric D Nacsa et al.
Organic letters, 15(1), 38-41 (2012-12-15)
The cyclopropenone catalyzed nucleophilic substitution of alcohols by methanesulfonate ion with inversion of configuration is described. This work provides an alternative to the Mitsunobu reaction that avoids the use of azodicarboxylates and generation of hydrazine and phosphine oxide byproducts. This
Siddheshwar K Chauthe et al.
Bioorganic & medicinal chemistry letters, 22(6), 2251-2256 (2012-02-22)
A series of dimeric phloroglucinol compounds were synthesized in a single step using commercially available phloroglucinol and methanesulfonic acid. Based on the reported anticancer activity of plant derived dimeric phloroglucinols, these synthesized compounds were evaluated for their in vitro anti-proliferative
Renata Solarska et al.
Nanoscale, 4(5), 1553-1556 (2012-02-01)
Nanostructuring of semiconductor films offers the potential means for producing photoelectrodes with improved minority charge carrier collection. Crucial to the effective operation of the photoelectrode is also the choice of a suitable electrolyte. The behaviour of the nanostructured WO(3) photoanodes
문서
Access gold precatalysts, silver salts, and unsaturated building blocks to accelerate research success in catalysis applications.
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