61626
Boron trifluoride methanol complex solution
13-15% BF3 basis
동의어(들):
BF3MeOH, Boron fluoride methanol, Boron trifluoride methanol, Boron trifluoride-methanol Complex
로그인조직 및 계약 가격 보기
모든 사진(1)
About This Item
Linear Formula:
BF3 · 2CH3OH
CAS Number:
Molecular Weight:
131.89
Beilstein:
3693581
MDL number:
UNSPSC 코드:
12352104
PubChem Substance ID:
NACRES:
NA.22
추천 제품
Quality Level
반응 적합성
core: boron
reagent type: Lewis acid
reagent type: catalyst
농도
12.5-15.5% boron trifluoride
density
0.859 g/mL at 25 °C
작용기
hydroxyl
SMILES string
CO.FB(F)F
InChI
1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;
InChI key
JBXYCUKPDAAYAS-UHFFFAOYSA-N
일반 설명
BF3-MeOH solution is a Lewis acid-base complex used as a versatile reagent and catalyst in organic synthesis.
애플리케이션
Boron trifluoride-methanol complex solution can be used for the deprotection of acetylated amines of cyanine dyes to form products with free amino groups. It may be used for the conversion of sulfur-containing phosphoramidates to the corresponding phosphate methyl ester.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1
표적 기관
Eyes,Central nervous system, Kidney
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point (°F)
60.8 °F - closed cup
Flash Point (°C)
16 °C - closed cup
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Boron trifluoride?methanol complex?mild and powerful reagent for deprotection of labile acetylated amines.
Miltsov S
Tetrahedron Letters, 44(11), 2301-2303 (2003)
Methanolysis of phosphoramidates with boron trifluoride-methanol complex.
Ryu S
The Journal of Organic Chemistry, 56(16), 4999-5002 (1991)
C Hue-Beauvais et al.
Journal of animal science, 93(4), 1641-1655 (2015-05-29)
Alterations to the metabolic endocrine environment during early life are crucial to mammary gland development. Among these environmental parameters, the initial nutritional event after birth is the consumption of milk, which represents the first maternal support provided to mammalian newborns.
Leila Nejadsadeghi et al.
Molecular biology reports, 42(2), 363-372 (2014-10-01)
Plant cells often increase cold tolerance by reprogramming their genes expression which results in adjusted metabolic alternations, a process enhanced under cold acclimation. In present study, we assessed the changes of membrane fatty acid compositions along with physio-biochemical indices like
Shulin Xiang et al.
Journal of pineal research, 59(1), 60-69 (2015-04-11)
Chemotherapeutic resistance, particularly to doxorubicin (Dox), represents a major impediment to successfully treating breast cancer and is linked to elevated tumor metabolism and tumor over-expression and/or activation of various families of receptor- and non-receptor-associated tyrosine kinases. Disruption of circadian time
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