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Merck
모든 사진(4)

주요 문서

B1252

Sigma-Aldrich

Boron trifluoride-methanol solution

14% in methanol

동의어(들):

BF3 methanol, BF3MeOH, Boron Trifluoride - Methanol Complex, Boron fluoride methanol, Boron trifluoride methanol, Boron trifluoride-methanol complex, Borontrifluoride methanol, Trifluoroborane

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About This Item

Linear Formula:
BF3 · MeOH
CAS Number:
Molecular Weight:
99.85
Beilstein:
3611499
MDL number:
UNSPSC 코드:
12352104
PubChem Substance ID:
NACRES:
NA.23

양식

liquid

Quality Level

반응 적합성

reagent type: catalyst
core: boron

농도

12-16% (titration by NaOH)
14% in methanol

density

0.859 g/mL at 25 °C

저장 온도

2-8°C

SMILES string

CO.FB(F)F

InChI

1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;

InChI key

JBXYCUKPDAAYAS-UHFFFAOYSA-N

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일반 설명

Boron trifluoride-methanol (BF-M) is an esterification reagent. BF-M is a powerful acidic catalyst for the esterification of the fatty acids. It easily cleaves acetylated dyes resulting in free amino groups. BF-M catalyzed trans esterification of vegetable oils forms biodiesel.

애플리케이션

Used in the deactylation of acetanilides.It is also used to study the synthesis of amino group containing cyanine dyes of different types and to prepare fatty acid methyl esters.

포장

Bottle with screw-cap closure.

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1

표적 기관

Eyes,Central nervous system, Kidney

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

49.5 °F

Flash Point (°C)

9.7 °C

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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시험 성적서(COA)

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문서 라이브러리 방문

Deacylation of N-Acetylated Amines with Alcohol and Boron Trifluoride.
Acta Chemica Scandinavica, 8, 529-530 (1954)
Martin Trépanier et al.
Applied and environmental microbiology, 71(9), 5341-5347 (2005-09-10)
Lipids are the major form of carbon storage in arbuscular-mycorrhizal fungi. We studied fatty acid synthesis by Glomus intraradices and Gigaspora rosea. [(14)C]Acetate and [(14)C]sucrose were incorporated into a synthetic culture medium to test fatty acid synthetic ability in germinating
Eun-Young Kim et al.
Molecular neurobiology, 57(9), 3860-3874 (2020-07-03)
Early life and adulthood stress increase vulnerability for mental illness, and eventually trigger depression. N-3 polyunsaturated fatty acids (PUFA) have antidepressant effects, but their effect on rats exposed to combined stress has been not investigated. This study aimed to investigate
Boron trifluoride-methanol complex-mild and powerful reagent for deprotection of labile acetylated amines.
Tetrahedron Letters, 44(11), 2301-2303 (2003)
Donghee Kim et al.
The British journal of nutrition, 121(2), 137-145 (2018-12-07)
Conversion of α-linolenic acid (ALA) into the longer chain n-3 PUFA has been suggested to be affected by the dietary intake of linoleic acid (LA), but the mechanism is not well known. Therefore, the purpose of this study was to

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