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Merck
모든 사진(2)

문서

697265

Sigma-Aldrich

Tetrakis(triphenylphosphine)palladium(0)

≥99.99% trace metals basis

동의어(들):

Palladium-tetrakis(triphenylphosphine), Pd(PPh3)4

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모든 사진(2)

About This Item

Linear Formula:
Pd[(C6H5)3P]4
CAS Number:
14221-01-3
Molecular Weight:
1155.56
Beilstein:
6704828
EC Number:
238-086-9
MDL number:
MFCD00010012
UNSPSC 코드:
12161600
PubChem Substance ID:
329761903
NACRES:
NA.22

분석

≥99.99% trace metals basis

형태

crystals

반응 적합성

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

저장 온도

2-8°C

SMILES string

[Pd].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12

InChI

1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;

InChI key

NFHFRUOZVGFOOS-UHFFFAOYSA-N

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관련 카테고리

픽토그램

Exclamation mark
GHS07

신호어

Warning

유해 및 위험 성명서

H302

예방조치 성명서

P264 - P270 - P301 + P312 - P501

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type N95 (US)

시험 성적서(COA)

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문서 라이브러리 방문

Wenhan Zhang et al.
Angewandte Chemie (International ed. in English), 53(34), 8980-8984 (2014-07-01)
tert-Butoxyacetylene is shown to undergo Sonogashira coupling with aryl iodides to yield aryl-substituted tert-butyl ynol ethers. These intermediates participate in a [1,5]-hydride shift, which results in the extrusion of isobutylene and the generation of aryl ketenes. The ketenes are trapped
Chanchal Chakraborty et al.
ACS applied materials & interfaces, 7(34), 19034-19042 (2015-08-19)
A platinum(II)-based, luminescent, metallo-supramolecular polymer (PolyPtL1) having an inherent dipole moment was synthesized via complexation of Pt(II) ions with an asymmetric ligand L1, containing terpyridyl and pyridyl moieties. The synthesized ligand and polymer were well characterized by various NMR techniques
Debabrata Jana et al.
Organic & biomolecular chemistry, 13(43), 10663-10674 (2015-09-09)
Four pyrene-vinyl-tetraphenylethylene based conjugated materials were synthesized and characterized by FT-IR, NMR, and mass spectroscopy. The photophysical (including absorption, fluorescence, and fluorescence lifetime) and aggregation properties in tetrahydrofuran were investigated. The photophysical and aggregation behavior depends on the spacer, substituent
Shouchun Yin et al.
Soft matter, 11(22), 4424-4429 (2015-05-01)
In this paper, a pyrene moiety is incorporated into a bolaamphiphile to form a novel molecule denoted PRB. Above the critical micelle concentration, PRB forms nanodisks in the aqueous solution. The addition of acetate ions induces a morphological change in
Haiyin Li et al.
Macromolecular bioscience, 14(10), 1361-1367 (2014-06-14)
Phospholipid monomer and aggregation-induced emission (AIE) dye-based dimers are incorporated via reversible addition-fragmentation transfer polymerization to afford cross-linked zwitterionic fluorescent copolymers. Such copolymers are prone to self-assembly into fluorescent polymeric nanoparticles (FPNs) in physiological solution due to their amphiphilic nature.

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