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Merck
모든 사진(1)

문서

157791

Sigma-Aldrich

Phosphorus trichloride

ReagentPlus®, 99%

동의어(들):

Phosphorus(III) chloride

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About This Item

Linear Formula:
PCl3
CAS Number:
Molecular Weight:
137.33
Beilstein:
969177
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.21

vapor density

4.75 (vs air)

Quality Level

vapor pressure

100 mmHg ( 20 °C)
125 mmHg ( 25 °C)
385 mmHg ( 55 °C)

제품 라인

ReagentPlus®

분석

99%

형태

liquid

refractive index

n20/D 1.5148 (lit.)

bp

74-78 °C (lit.)

mp

−112 °C (lit.)

density

1.574 g/mL at 20 °C (lit.)

SMILES string

ClP(Cl)Cl

InChI

1S/Cl3P/c1-4(2)3

InChI key

FAIAAWCVCHQXDN-UHFFFAOYSA-N

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일반 설명

Phosphorus trichloride is a slightly yellow or colorless fuming liquid, which finds applications in electrodeposition of metal on rubber and in the preparation of pesticides. It can undergo reaction with chlorine gas to form phosphorus pentachloride.
Rotational spectra of phosphorus trichloride has been studied in the microwave region. Its reaction with unsaturated compounds in the presence of diacetyl peroxide has been reported.

애플리케이션

Phosphorus trichloride may be used in the preparation of following:
  • alkylphosphonyl dichlorides
  • benzidronate
  • 4-(dibromomethyl)-substituted benzenes bearing a phosphorus functional group in the side chain
  • dinucleoside phosphorochloridite

법적 정보

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

픽토그램

Skull and crossbonesHealth hazardCorrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 2 Inhalation

표적 기관

Respiratory Tract

보충제 위험성

Storage Class Code

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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시험 성적서(COA)

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Clugston, M. and Flemming, R
Advanced Chemistry (2000)
Synthesis and properties of 4-(dibromomethyl) benzenecarbaldehyde.
Gazizov MB, et al.
Tetrahedron Letters, 57(2), 210-212 (2016)
Yousef Beni et al.
Tetrahedron letters, 56(17), 2247-2250 (2015-12-15)
Dinucleoside phosphorochloridite were synthesized from phosphorus trichloride and three nucleoside analogues, 3'-fluoro-2',3'-dideoxythymidine (FLT), 2',3'-dideoxy-5-fluoro-3'-thiacytidine (FTC), and 2',3'-dideoxy-3'-thiacytidine (3TC), in a multistep synthesis. Polymer-bound
The microwave spectra and molecular structure of phosphorus and arsenic trichloride.
Kisliuk P and Townes CH.
J. Chem. Phys. , 18(8), 1109-1110 (1950)
661. Formation of organo-phosphorus compounds by the reaction of alkyl chlorides with phosphorus trichloride in the presence of aluminium chloride.
Kinnear AM and Perren EA.
Journal of the Chemical Society, 3437-3445 (1952)

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