772836

Isopropenylmagnesium bromide solution

1.0 M in 2-methyltetrahydrofuran

• Synonym(s): 1-Methylvinylmagnesium bromide, 1-Propen-2-ylmagnesium bromide, 2-Propen-2-ylmagnesium bromide, Bromo prop-1-en-2-yl magnesium, Bromo(isopropenylmagnesium), Isopropenylmagnesium bromide
• Linear Formula: CH₂=C(CH₃)MgBr
• CAS Number: 13291-18-4
• Molecular Weight: 145.28
• Beilstein/REAXYS Number: 3587297
• MDL number: MFCD00192240
• UNSPSC Code: 12352103
• PubChem Substance ID: 329766609
• EC Index Number: 603-688-6
• NACRES: NA.22

Properties

• form: solution
• reaction suitability: reaction type: Grignard Reaction
• greener alternative product characteristics: Safer Solvents and Auxiliaries; Use of Renewable Feedstocks; Inherently Safer Chemistry for Accident Prevention; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• concentration: 1.0 M in 2-methyltetrahydrofuran
• density: 0.970 g/mL
• greener alternative category: , Aligned
• storage temp.: 2-8°C
• SMILES string: CC(=C)[Mg]Br
• InChI: 1S/C3H5.BrH.Mg/c1-3-2;;/h1H2,2H3;1H;/q;;+1/p-1
• InChI key: LFTYALBVGVNGLI-UHFFFAOYSA-M

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Click here for more information.

Application

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Safety Information

• pictograms: GHS02,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H260,H302,H314
• pcodes: P210 - P231 + P232 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 1
• supp_hazards: EUH019
• Storage Class: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• wgk_germany: WGK 3
• flash_point_f: 57.2 °F - closed cup
• flash_point_c: 14 °C - closed cup