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79558

Sigma-Aldrich

Sodium phosphomolybdate hydrate

technical

Synonym(s):

Molybdophosphoric acid sodium salt, Phosphomolybdic acid sodium salt hydrate

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About This Item

Linear Formula:
Na3[P(Mo3O10)4] · xH2O
CAS Number:
Molecular Weight:
1891.20 (anhydrous basis)
EC Number:
MDL number:
UNSPSC Code:
12352000
PubChem Substance ID:
NACRES:
NA.22

grade

technical

form

crystals

reaction suitability

core: molybdenum
reagent type: catalyst
reagent type: oxidant

mp

98 °C (dec.) (lit.)

density

2.83 g/mL at 25 °C (lit.)

SMILES string

O.[Na+].[Na+].[Na+].[O-][Mo](=O)(=O)O[Mo](=O)(=O)O[Mo](=O)(=O)O[Mo](=O)(=O)OP(=O)(O[Mo](=O)(=O)O[Mo](=O)(=O)O[Mo](=O)(=O)O[Mo]([O-])(=O)=O)O[Mo](=O)(=O)O[Mo](=O)(=O)O[Mo](=O)(=O)O[Mo]([O-])(=O)=O

InChI

1S/12Mo.3Na.H3O4P.H2O.36O/c;;;;;;;;;;;;;;;1-5(2,3)4;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/h;;;;;;;;;;;;;;;(H3,1,2,3,4);1H2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/q;;;;;;;;;6*+1;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;3*-1/p-3

InChI key

GVSXYXXCIUVHQT-UHFFFAOYSA-K

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Application

Reactant for synthesis of:
  • Supramolecular hydrogen-bonded Archimedean cages with encapsulated organic and inorganic species

Reactant for:
  • Temperature programmed reduction and hydrogen-isotope exchange
  • Passivation of stainless steel

Used for:
  • Plastic membrane electrodes for determination of flavoxate hydrochloride and cyclopentolate hydrochloride
  • Investigations of catalyst load role on transesterification of di-Me carbonate and phenol
  • Cocatalyst for methanol carbonylation

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


Certificates of Analysis (COA)

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Dawei Fan et al.
Journal of colloid and interface science, 351(1), 151-155 (2010-08-19)
Hybrid films composed of oppositely charged Keggin-type 12-molybdophosphoric acid H(3)PMo(12)O(40).nH(2)O (PMo(12)) and water-soluble cationic meso-tetra (N-methyl-4-pyridyl) porphinetetratosylate (TMPyP) were fabricated onto silicon and ITO substrates by a layer-by-layer (LbL) self-assembly technique. The LbL films were characterized by UV-vis spectroscopy, X-ray
Rubel Chakravarty et al.
Journal of chromatography. A, 1220, 82-91 (2011-12-27)
Barium-137m availed from a (137)Cs/(137m)Ba generator is an attractive industrial radiotracer for liquid flow rate measurement owing to its short half-life (T(1/2)=2.5 min) and emission of highly energetic gamma radiation (E(γ)=661.7 keV). Ammonium molybdophosphate (AMP) impregnated alumina microspheres (AMP-Al(2)O(3)), an
Maher Mahmoud El-Hashash et al.
Acta pharmaceutica (Zagreb, Croatia), 60(3), 361-367 (2010-12-08)
In the present study, antioxidant activity of methanolic extracts of the leaves of seven Egyptian Cassia species was investigated using two methods, the phosphomolyb-date method and 1,1 diphenyl-2-picrylhydrazyl radical (DPPH) scavenging activity method.· The results revealed that C. glauca is
Rasha M El-Nashar et al.
Analytica chimica acta, 730, 99-111 (2012-05-29)
This work offers construction and comparative evaluation the performance characteristics of conventional polymer (I), carbon paste (II) and carbon nanotubes chemically modified carbon paste ion selective electrodes (III) for meclofenoxate hydrochloride are described. These electrodes depend mainly on the incorporation
Almino Afonso de O Paiva et al.
International immunopharmacology, 11(9), 1241-1250 (2011-04-21)
This study analyzes the action of sulfated polysaccharides, fucans, from algae Lobophora variegata on zymosan-induced arthritis in rats. Groups of fucans, obtained after acetone fractionation (0.3-2.0 volumes), were denominated F0.3, F0.5, F0.8, F1, F1.5, and F2. The results that F1

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