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900540

Sigma-Aldrich

Ir(dFppy)3

Synonym(s):

tris[3,5-difluoro-2-(2-pyridinyl)phenyl]-Iridium

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About This Item

Empirical Formula (Hill Notation):
C33H18F6IrN3
CAS Number:
387859-70-3
Molecular Weight:
762.72
UNSPSC Code:
12161600
NACRES:
NA.22

form

powder or crystals

Quality Level

100

reaction suitability

core: iridium
reaction type: Photocatalysis
reagent type: catalyst

mp

401 °C

photocatalyst activation

450 nm

SMILES string

FC1=CC([Ir]C2=C(C3=NC=CC=C3)C(F)=CC(F)=C2)=C(C4=NC=CC=C4)C(F)=C1.FC5=CC(F)=CC=C5C6=NC=CC=C6

InChI

1S/3C11H6F2N.Ir/c3*12-8-4-5-9(10(13)7-8)11-3-1-2-6-14-11;/h3*1-4,6-7H;

InChI key

GFSFWLGQTIKUOK-UHFFFAOYSA-N

Application

Ir(dFppy)3 is a photocatalyst that readily facilitates the decarboxylative arylation of α amino acids using visible light.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Citation

Decarboxylative Arylation of α-Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass to Drug Pharmacophore

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Product No.
Description
Pricing

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCT7725
MKCL8214

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