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905100

Sigma-Aldrich

Ir(p-tBu-ppy)3

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About This Item

Empirical Formula (Hill Notation):
C45H48IrN3
CAS Number:
1396451-04-9
Molecular Weight:
823.10
UNSPSC Code:
12352101
NACRES:
NA.22

form

powder

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

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Product No.
Description
Pricing

688096

Tris[2-phenylpyridinato-C2,N]iridium(III), 97%

900540

Ir(dFppy)3

900539

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Ir(p-CF3-ppy)3, ≥95%

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Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Xiao-Jing Wei et al.
ACS catalysis, 7(10), 7136-7140 (2017-11-08)
The development of synthetic methodologies which provide access to both stereoisomers of α,β-disubstituted olefins is a challenging undertaking. Herein, we describe the development of an operationally simple and stereoselective synthesis of difluoromethylated styrenes via a visible-light photocatalytic decarboxylation strategy using
Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis
Singh A, et al.
Journal of Organometallic Chemistry, 776, 51-59 (2015)
Eric D Nacsa et al.
Journal of the American Chemical Society, 140(9), 3322-3330 (2018-02-06)
Nature routinely engages alcohols as leaving groups, as DNA biosynthesis relies on the removal of water from ribonucleoside diphosphates by a radical-mediated "spin-center shift" (SCS) mechanism. Alcohols, however, remain underused as alkylating agents in synthetic chemistry due to their low
Amandeep Arora et al.
Organic letters, 18(16), 3996-3999 (2016-08-06)
The 2-azolyl radical, generated from 2-bromoazoles via photocatalysis, is a powerful intermediate for the intermolecular arylation of unmodified (hetero)arenes. The reaction is characterized by mild conditions, operational simplicity, tolerance toward functional and sterically demanding groups, broad scope, and anti-Minisci selectivity.

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