904694
Ir(p-CF3-ppy)3
≥95%
Synonym(s):
Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium
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All Photos(3)
About This Item
Empirical Formula (Hill Notation):
C36H21F9IrN3
CAS Number:
Molecular Weight:
858.77
UNSPSC Code:
12161600
NACRES:
NA.22
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assay
≥95%
form
powder or crystals
reaction suitability
core: iridium
reagent type: catalyst
reaction type: Photocatalysis
mp
>300 °C
photocatalyst activation
465 nm
Application
This photocatalyst facilitates a variety of transformations using visible light, including the defluorination of arenes.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
related product
Product No.
Description
Pricing
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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A Singh et al.
Chemical science, 6(12), 7206-7212 (2015-12-01)
C-F functionalizations that provide C-C bonds are challenging synthetic transformations, due in part to the large C-F bond strength, short bond length, nonpolarizable nature, the production of fluoride, and the regioselectivity-in the case of multifluorinated substrates. However, commercially available highly
Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis
Singh A, et al.
Journal of Organometallic Chemistry, 776, 51-59 (2015)
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