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Solvent-induced invesrsion of enantioselectivity during esterification of 2-phenoxypropionic acid catalyzed by Candida cylindracea lipase has been investigated. Derivatives of 2-phenoxypropionic acid are potential herbicides.
保管分類コード
11 - Combustible Solids
WGK
WGK 1
引火点(°F)
Not applicable
引火点(℃)
Not applicable
適用法令
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Jan Code
197149-BULK:
197149-50G:
197149-VAR:
Manuel A P Segurado et al.
The Journal of organic chemistry, 72(14), 5327-5336 (2007-06-15)
Rate constants were measured for the oxidative chlorodehydrogenation of (R,S)-2-phenoxypropanoic acid and nine ortho-, ten para- and five meta-substituted derivatives using (R,S)-1-chloro-3-methyl-2,6-diphenylpiperidin-4-one (NCP) as chlorinating agent. The kinetics was run in 50% (v/v) aqueous acetic acid acidified with perchloric acid
Lipase-catalyzed production of optically active acids via asymmetric hydrolysis of esters.
Cambou B and Klibanov AM.
Applied Biochemistry and Biotechnology, 9(3), 255-260 (1984)
Solvent-induced inversion of enantiosflectivity in lipase-catalyzed esterification of 2-phenoxypropionic acids.
Ueji S, et al.
Biotechnology Letters, 14(3), 163-168 (1992)
Yan He et al.
Journal of pharmaceutical sciences, 95(1), 97-107 (2005-11-30)
The efficiency of a solubilization technique is determined by the physical-chemical properties of the drug. This study investigates the solubilization on two structurally related anticancer drugs, XK-469 and PPA. XK-469 is much less polar than PPA with an intrinsic solubility
Jessica Lin et al.
Journal of chromatography. A, 1624, 461244-461244 (2020-06-17)
Analysis and control of stereoisomers is a major task in pharmaceutical analysis, and is a greater challenge when compounds with multiple chiral centers (MCC) are concerned. HPLC and SFC are commonly used for stereoisomer analysis in drug development, typically starting
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