79989

テトラブチルアンモニウムシアニド

technical, ≥80%

• 別名: N,N,N-tributyl-1-butanaminium cyanide
• 化学式: (CH₃CH₂CH₂CH₂)₄N(CN)
• CAS番号: 10442-39-4
• 分子量: 268.48
• Beilstein: 3598808
• EC Number: 233-926-0
• MDL番号: MFCD00043221
• UNSPSCコード: 12352116
• PubChem Substance ID: 329768102
• NACRES: NA.22

特性

• グレード: technical
• 品質水準: 100
• アッセイ: ≥80%
• フォーム: crystals
• mp: 89-92 °C (lit.)
• SMILES記法: [C-]#N.CCCC[N+](CCCC)(CCCC)CCCC
• InChI: 1S/C16H36N.CN/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-2/h5-16H2,1-4H3;/q+1;-1
• InChI Key: KRRBFUJMQBDDPR-UHFFFAOYSA-N

詳細

アプリケーション

Tetrabutylammonium cyanide can be used as a catalyst:

• For the deprotection of aliphatic thioacetate to synthesize free thiols in the presence of a protic solvent.
• In the O-TMS cyanosilylation of carbonyl compounds to synthesize cyanohydrin trimethylsilyl ethers in the presence of trimethylsilyl cyanide (TMSCN).
• For the ring expansion of β-lactams to synthesize γ-lactams through a bond cleavage of the β-lactam in the presence of acetonitrile.

安全性情報

• ピクトグラム: GHS06,GHS09
• シグナルワード: Danger
• 危険有害性情報: H300 + H310 + H330,H410
• 注意書き: P262 - P264 - P273 - P280 - P302 + P352 + P310 - P304 + P340 + P310
• 危険有害性の分類: Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1
• 補足的ハザード: EUH032
• 保管分類コード: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges