00375

4-アセトアミド-2,2,6,6-テトラメチルピペリジン 1-オキシル

purum, ≥98.0% (HPLC)

• 実験式（ヒル表記法）: C₁₁H₂₁N₂O₂
• CAS番号: 14691-89-5
• 分子量: 213.30
• Beilstein: 3546225
• EC Number: 423-840-3
• MDL番号: MFCD00043593
• UNSPSCコード: 12352005
• PubChem Substance ID: 329747053
• NACRES: NA.22

特性

• グレード: purum
• 品質水準: 200
• アッセイ: ≥98.0% (HPLC)
• 環境により配慮した代替製品スコア: old score: 9; new score: 8; Find out more about DOZN™ Scoring
• 環境により配慮した代替製品の特徴: Waste Prevention; Safer Solvents and Auxiliaries; Inherently Safer Chemistry for Accident Prevention; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 143-145 °C (lit.); 143-146 °C
• 官能基: amide
• 環境により配慮した代替製品カテゴリ: , Re-engineered
• 保管温度: 2-8°C
• SMILES記法: CC(=O)NC1CC(C)(C)N([O])C(C)(C)C1
• InChI: 1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)
• InChI Key: UXBLSWOMIHTQPH-UHFFFAOYSA-N

詳細

詳細

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by ¹H, ¹³C and ¹⁵N NMR spectral data.

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives . This product belongs to category of Re-engineered products, showing key improvements in Green Chemistry Principles “Waste Prevention”, “Safer Solvents and Auxiliaries” and “Inherently Safer Chemistry for Accident Prevention”. Click here to view its DOZN scorecard.

アプリケーション

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.

その他情報

New oxidant for the mild oxidation of alcohols to carbonyls

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H302
• 注意書き: P264 - P270 - P301 + P312 - P501
• 危険有害性の分類: Acute Tox. 4 Oral
• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 1
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): dust mask type N95 (US), Eyeshields, Gloves