29140

シクロヘキサノン

puriss. p.a., ≥99.5% (GC)

• 別名: pimelic ketone
• 化学式: C₆H₁₀(=O)
• CAS番号: 108-94-1
• 分子量: 98.14
• Beilstein: 385735
• EC Number: 203-631-1
• MDL番号: MFCD00001625
• UNSPSCコード: 12352100
• PubChem Substance ID: 57648345
• NACRES: NA.21

特性

• 蒸気密度: 3.4 (vs air)
• 品質水準: 200
• 蒸気圧: 3.4 mmHg ( 20 °C)
• グレード: puriss. p.a.
• アッセイ: ≥99.5% (GC)
• 自己発火温度: 788 °F
• expl. lim.: 1.1 %, 100 °F; 9.4 %
• 不純物: ≤0.5% water
• 蒸発残留物質: ≤0.05%
• 屈折率: n20/D 1.450 (lit.); n20/D 1.450
• bp: 155 °C (lit.)
• mp: −47 °C (lit.)
• 密度: 0.947 g/mL at 25 °C (lit.)
• 微量陽イオン: Al: ≤0.5 mg/kg; Ba: ≤0.1 mg/kg; Bi: ≤0.1 mg/kg; Ca: ≤0.5 mg/kg; Cd: ≤0.05 mg/kg; Co: ≤0.02 mg/kg; Cr: ≤0.02 mg/kg; Cu: ≤0.02 mg/kg; Fe: ≤0.1 mg/kg; K: ≤0.5 mg/kg; Li: ≤0.1 mg/kg; Mg: ≤0.1 mg/kg; Mn: ≤0.02 mg/kg; Mo: ≤0.1 mg/kg; Na: ≤0.5 mg/kg; Ni: ≤0.02 mg/kg; Pb: ≤0.1 mg/kg; Sr: ≤0.1 mg/kg; Zn: ≤0.1 mg/kg
• 官能基: ketone
• SMILES記法: O=C1CCCCC1
• InChI: 1S/C6H10O/c7-6-4-2-1-3-5-6/h1-5H2
• InChI Key: JHIVVAPYMSGYDF-UHFFFAOYSA-N

詳細

詳細

Cyclohexanone is a cyclic ketone mainly used as an intermediate in the synthesis of nylon.

アプリケーション

Cyclohexanone may undergo asymmetric Michael addition with aryl and alkyl nitroolefins in the presence of pyrrolidine-urea based catalysts to form the corresponding adducts. It may also be used in the synthesis of a wide range of compounds such as adipic acid, 2-(hydroxy(phenyl)methyl)cyclohexanone, 2-allylcyclohexan-1-one, tetrasubstituted propargylamines and N-cyclohexyl-benzyl amine derivatives.

安全性情報

• ピクトグラム: GHS02,GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H226,H302 + H312 + H332,H315,H318,H335
• 注意書き: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 1
• 引火点(°F): 111.2 °F - closed cup
• 引火点(℃): 44 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter