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Merck
모든 사진(1)

주요 문서

324450

Sigma-Aldrich

(S)-(+)-1-(2-Pyrrolidinylmethyl)pyrrolidine

96%

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About This Item

실험식(Hill 표기법):
C9H18N2
CAS Number:
Molecular Weight:
154.25
MDL number:
UNSPSC 코드:
12352005
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

96%

광학 활성

[α]19/D +7.0°, c = 2.4 in ethanol

refractive index

n20/D 1.4871 (lit.)

bp

99-101 °C/2 mmHg (lit.)

density

0.946 g/mL at 25 °C (lit.)

SMILES string

C1CCN(C1)C[C@@H]2CCCN2

InChI

1S/C9H18N2/c1-2-7-11(6-1)8-9-4-3-5-10-9/h9-10H,1-8H2/t9-/m0/s1

InChI key

YLBWRMSQRFEIEB-VIFPVBQESA-N

애플리케이션

(S)-(+)-1-(2-Pyrrolidinylmethyl)pyrrolidine can be used as an organocatalyst in the asymmetric synthesis of different optically active organic building blocks via Aldol condensation and Mannich reactions . It is also used as a catalyst to prepare enantioselective Michael adducts by reacting alkylidene malonates with unactivated ketones.

픽토그램

Exclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point (°F)

190.4 °F - closed cup

Flash Point (°C)

88 °C - closed cup

개인 보호 장비

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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시험 성적서(COA)

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문서 라이브러리 방문

Catalytic enantioselective direct Michael additions of ketones to alkylidene malonates
Betancort JM, et al.
Tetrahedron Letters, 42(27), 4441-4444 (2001)
M Guipponi et al.
Human genetics, 109(6), 569-575 (2002-01-26)
The human TPTE gene encodes a testis-specific protein that contains four potential transmembrane domains and a protein tyrosine phosphatase motif, and shows homology to the tumor suppressor PTEN/MMAC1. Chromosomal mapping revealed multiple copies of the TPTE gene present on the
Shoujiro Ogawa et al.
Biomedical chromatography : BMC, 30(1), 29-34 (2015-01-27)
A simple liquid chromatography/electrospray ionization-tandem mass spectrometry (LC/ESI-MS/MS) method for determination of the eicosapentaenoic acid (EPA) concentration to arachidonic acid (AA) concentration ratio in human saliva has been developed. The EPA/AA ratio in serum or plasma is widely recognized as
(S)-(+)-1-(2-pyrrolidinylmethyl)pyrrolidine ? an effective catalyst of asymmetric synthesis
VM Tkachuk, et al.
Zhurnal Organichnoi ta Farmatsevtichnoi Khimii, 3-16 (2014)
Nathalie Petit et al.
Human molecular genetics, 12(9), 1045-1053 (2003-04-18)
Rigid spine muscular dystrophy and the classical form of multiminicore disease are caused by mutations in SEPN1 gene, leading to a new clinical entity referred to as SEPN1-related myopathy. SEPN1 codes for selenoprotein N, a new member of the selenoprotein

문서

Chiral vicinal diamines are of tremendous interest to the synthetic chemist as they are found in many chiral catalysts and pharmaceuticals.

자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..

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