683396

[Pd(allyl)Cl]₂

Umicore

• 동의어(들): Allylpalladium(II) chloride dimer, Allylchloropalladium dimer, Bis(η³-allyl)di(μ-chloro)dipalladium(II), Bis(allyl)dichlorodipalladium, Bis(allyl)dichloropalladium, Bis(allylchloropalladium), Diallyldichlorodipalladium, [PdCl(C₃H₅)]₂
• 실험식(Hill 표기법): C₆H₁₀Cl₂Pd₂
• CAS Number: 12012-95-2
• Molecular Weight: 365.89
• Beilstein: 4124623
• EC Number: 234-579-8
• MDL number: MFCD00044874
• UNSPSC 코드: 12161600
• PubChem Substance ID: 329760817
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: ≥98.0% (C, elemental analysis)
• 양식: solid
• 반응 적합성: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• 저장 온도: 2-8°C
• SMILES string: Cl[Pd]CC=C.Cl[Pd]CC=C
• InChI: 1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2
• InChI key: TWKVUTXHANJYGH-UHFFFAOYSA-L

설명

애플리케이션

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

[Pd(allyl)Cl]₂ can be used as a catalyst:

• For the silylation of organobromides.
• To synthesize α-aryl carbonyl compounds by coupling reaction between aldehydes and aryl halides.
• To prepare various arylthiophene derivatives by cross-coupling reaction with aryl halides via C-H functionalization.

기타 정보

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

법적 정보

Product of Umicore

Additional information available at www.pmc.umicore.com

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315
• 예방조치 성명서: P264 - P280 - P302 + P352 - P332 + P313 - P362 + P364
• Hazard Classifications: Skin Irrit. 2
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Faceshields, Gloves